Synthesis of hybrid polymethacrylate-noble metal (M = Au, Pd) nanoparticles for the growth of metal-oxide semiconductor nanowires
Turcu, R. P.
Google Scholar check
MetadataShow full item record
Metal-oxide semiconductor nanowires (NWs) such as ZnO, β-Ga 2O 3 and SnO 2 with diameters of tens of nanometres and lengths of many micrometres have been grown using micellar nanohybrids consisting of methacrylate-based diblock copolymers and noble metal nanoparticles (MNPs). Micellar Au and Pd MNPs with diameters as small as 2.3 ± 0.3 nm were deposited on Si(001) by spin coating or drop casting and metal-oxide NWs were grown by reactive vapor transport. A high yield of β-Ga 2O 3 NWs with diameters of approximately 40 nm, lengths > 10 μm and a monoclinic crystal structure were obtained at 900 °C with the largest MNPs. These exhibited a broad, symmetric photoluminescence (PL) spectrum centred at 2.3 eV attributed to defect states situated energetically in the energy band gap of β-Ga 2O 3. We find that a reduction in the size of the MNPs below 10 nm leads to the formation of necklace like β-Ga 2O 3 NWs via the encapsulation of the MNPs which act as catalytic centres for the formation of branched nanostructures along the length of the β-Ga 2O 3 NWs that are also responsible for a blue shift in the PL at 2.8 eV as a result of quantum confinement. This was not observed upon reducing the density of MNPs or in the case of ZnO or SnO 2 NWs grown with the smallest of MNPs probably due to differences in surface energy. We show that polymethacrylate-noble MNPs may be patterned directly by electron beam lithography and may be exploited for the selective location growth of semiconductor NWs while we also discuss the difference between the sizes of the hybrid polymer-MNPs and MO NWs which is attributed to agglomeration. © The Royal Society of Chemistry 2012.
Showing items related by title, author, creator and subject.
Effects of sol-gel synthesis on 5Fe-15Mn-40Zn-40Ti-O mixed oxide structure and its H2S removal efficiency from industrial gas streams Polychronopoulou, Kyriaki; Efstathiou, Angelos M. (2009)A novel Fe-Mn-Zn-Ti-O mixed metal oxide has been developed for efficient low-temperature (25-50°C) removal of H2S from a gas mixture containing 600 ppm H2S, 25 vol% H2, 7.5 vol % CO 2, and 1-3 vol% H2O that simulates typical ...
Using statistical analysis as an additional tool in porous solid characterization Attipa, Christothea; Panayiotou, Antonia; Kokkinofta, Rebecca I.; Theocharis, Charis R. (2011)Analytical chemists have long used statistical methods to help them organize and interpret experimental data-especially where large numbers of these are generated-as well as to help them design new experiments. Recently, ...
Low-temperature catalytic decomposition of ethylene into H2 and secondary carbon nanotubes over Ni/CNTs Savva, Petros G.; Polychronopoulou, Kyriaki; Ryzkov, V. A.; Efstathiou, Angelos M. (2010)The present work reports on the production of H2 and secondary carbon nanotubes (CNTs) during catalytic decomposition of ethylene over a novel catalytic system, namely, nickel supported on carbon nanotubes (Ni/CNTs) at ...