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dc.contributor.authorChronakis, Nikosen
dc.contributor.authorHirsch, A.en
dc.creatorChronakis, Nikosen
dc.creatorHirsch, A.en
dc.date.accessioned2019-11-21T06:17:46Z
dc.date.available2019-11-21T06:17:46Z
dc.date.issued2006
dc.identifier.issn1631-0748
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55348
dc.description.abstractThe tether-directed remote functionalization of C60 has been investigated by using cyclic bis- and trismalonate tethers. The reactive malonate groups are connected with alkyl spacers and their synthesis was performed in one step by the condensation reaction of malonyl dichloride with an appropriate diol. Macrocycles containing identical alkyl spacers afforded bis- and triadducts of C60 with rotational symmetry in a regioselective manner and in remarkable yields. In contrast, macrocycles bearing different alkyl spacers led to the formation of Cs-symmetrical bisadducts. Tuning of the spacer's length gave access to different addition patterns of C60 while, the synthesis of enantiomerically pure trisadducts of C60 with an e,e,e-addition pattern was achieved via cyclopropanation with chiral D3-symmetrical cyclo-tris-malonate tethers. To cite this article: N. Chronakis et A. Hirsch. C. R. Chimie 8 (2005). © 2006 Académie des sciences.en
dc.sourceComptes Rendus Chimieen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-33646524051&doi=10.1016%2fj.crci.2005.11.006&partnerID=40&md5=6facb765b9f2fd5eecb16fe41dae45d8
dc.subjectRegioselectivityen
dc.subjectAddition patternen
dc.subjectFunctionalizationen
dc.subjectInherently chiralen
dc.subjectMacrocyclic malonatesen
dc.subjectRegioisomersen
dc.subjectSpaceren
dc.titleMacrocyclic malonates. A new family of tethers for the regio- and diastereoselective functionalization of [60]fullereneen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1016/j.crci.2005.11.006
dc.description.volume9
dc.description.issue7-8
dc.description.startingpage862
dc.description.endingpage867
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :15</p>en
dc.source.abbreviationC.R.Chim.en
dc.contributor.orcidChronakis, Nikos [0000-0002-2726-5290]


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