dc.contributor.author | Kabanos, Themistoklis A. | en |
dc.contributor.author | Keramidas, Anastasios D. | en |
dc.contributor.author | Mentzafos, D. | en |
dc.contributor.author | Russo, U. | en |
dc.contributor.author | Terzis, Aris | en |
dc.contributor.author | Tsangaris, John Michael | en |
dc.creator | Kabanos, Themistoklis A. | en |
dc.creator | Keramidas, Anastasios D. | en |
dc.creator | Mentzafos, D. | en |
dc.creator | Russo, U. | en |
dc.creator | Terzis, Aris | en |
dc.creator | Tsangaris, John Michael | en |
dc.date.accessioned | 2019-11-21T06:19:32Z | |
dc.date.available | 2019-11-21T06:19:32Z | |
dc.date.issued | 1992 | |
dc.identifier.issn | 1472-7773 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55590 | |
dc.description.abstract | The tin(IV) complexes [SnX4L] [L = 2-(2-pyridyl)benzimidazole | en |
dc.description.abstract | X = Cl, Br or I] and [SnMe2Cl2L] were prepared by a dehydration reaction of N-(2-aminophenyl)pyridine-2-carboxamide L′ with either SnX4 (X = Cl, Br or I) or SnMe2Cl2 in chloroform solution. The X-ray crystal structures of [SnMe2Cl2L] and [SnBr4L]·0.5MeNO2 show a distorted octahedral geometry around the tin(IV) atom in both molecules. The ligand L acts as a bidentate chelate with ligated atoms being the pyridine-type nitrogens of the heterocyclic rings. The chlorine atoms in [SnMe2Cl2L] are cis while the methyl groups are trans to each other, Infrared and Mössbauer spectra and a correlation of X-ray structural and anti-tumour (P388 lymphocytic leukaemia) data for the octahedral tin(IV) complexes are also reported. The X-ray structures are the first such reported for metal complexes containing 2-(2-pyridyl)benzimidazole. | en |
dc.source | Journal of the Chemical Society, Dalton Transactions | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-37049076610&doi=10.1039%2fDT9920002729&partnerID=40&md5=2f087a88079afb5fd295939678bdac7b | |
dc.title | Synthesis, structural and physical studies of tin(IV) complexes with 2-(2-pyridyl)benzimidazole | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/DT9920002729 | |
dc.description.issue | 18 | |
dc.description.startingpage | 2729 | |
dc.description.endingpage | 2733 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :42</p> | en |
dc.contributor.orcid | Keramidas, Anastasios D. [0000-0002-0446-8220] | |
dc.contributor.orcid | Kabanos, Themistoklis A. [0000-0001-6944-5153] | |
dc.gnosis.orcid | 0000-0002-0446-8220 | |
dc.gnosis.orcid | 0000-0001-6944-5153 | |