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dc.contributor.authorKabanos, Themistoklis A.en
dc.contributor.authorKeramidas, Anastasios D.en
dc.contributor.authorMentzafos, D.en
dc.contributor.authorRusso, U.en
dc.contributor.authorTerzis, Arisen
dc.contributor.authorTsangaris, John Michaelen
dc.creatorKabanos, Themistoklis A.en
dc.creatorKeramidas, Anastasios D.en
dc.creatorMentzafos, D.en
dc.creatorRusso, U.en
dc.creatorTerzis, Arisen
dc.creatorTsangaris, John Michaelen
dc.description.abstractThe tin(IV) complexes [SnX4L] [L = 2-(2-pyridyl)benzimidazoleen
dc.description.abstractX = Cl, Br or I] and [SnMe2Cl2L] were prepared by a dehydration reaction of N-(2-aminophenyl)pyridine-2-carboxamide L′ with either SnX4 (X = Cl, Br or I) or SnMe2Cl2 in chloroform solution. The X-ray crystal structures of [SnMe2Cl2L] and [SnBr4L]·0.5MeNO2 show a distorted octahedral geometry around the tin(IV) atom in both molecules. The ligand L acts as a bidentate chelate with ligated atoms being the pyridine-type nitrogens of the heterocyclic rings. The chlorine atoms in [SnMe2Cl2L] are cis while the methyl groups are trans to each other, Infrared and Mössbauer spectra and a correlation of X-ray structural and anti-tumour (P388 lymphocytic leukaemia) data for the octahedral tin(IV) complexes are also reported. The X-ray structures are the first such reported for metal complexes containing 2-(2-pyridyl)benzimidazole.en
dc.sourceJournal of the Chemical Society, Dalton Transactionsen
dc.titleSynthesis, structural and physical studies of tin(IV) complexes with 2-(2-pyridyl)benzimidazoleen
dc.description.endingpage2733 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied SciencesΤμήμα Χημείας / Department of Chemistry
dc.description.notes<p>Cited By :42</p>en
dc.contributor.orcidKeramidas, Anastasios D. [0000-0002-0446-8220]
dc.contributor.orcidKabanos, Themistoklis A. [0000-0001-6944-5153]

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