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Probing the nitrite and nitric oxide reductase activity of cbb3 oxidase: Resonance Raman detection of a six-coordinate ferrous heme-nitrosyl species in the binuclear b3/CuB center

dc.contributor.authorLoullis, Andreasen
dc.contributor.authorPinakoulaki, Eftychiaen
dc.creatorLoullis, Andreasen
dc.creatorPinakoulaki, Eftychiaen
dc.date.accessioned2019-11-21T06:21:17Z
dc.date.available2019-11-21T06:21:17Z
dc.date.issued2015
dc.identifier.issn1359-7345
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55813
dc.description.abstractIn this work we report the first spectroscopic evidence demonstrating that cbb3 oxidase catalyzes the reduction of nitrite to nitrous oxide under reducing anaerobic conditions. The reaction proceeds through the formation of a ferrous six-coordinate heme b3-nitrosyl species that has been characterized by resonance Raman spectroscopy. © The Royal Society of Chemistry 2015.en
dc.sourceChemical Communicationsen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84948799661&doi=10.1039%2fc5cc06802a&partnerID=40&md5=b3cc3c2ea4caccc9e8bc37e148cea6d2
dc.subjectcontrolled studyen
dc.subjectunclassified drugen
dc.subjectArticleen
dc.subjectsteady stateen
dc.subjectenzyme activityen
dc.subjectchemistryen
dc.subjectenzymologyen
dc.subjectoxidation reduction reactionen
dc.subjectOxidation-Reductionen
dc.subjectcopperen
dc.subjectinfrared spectroscopyen
dc.subjectelectron transporten
dc.subjectcysteineen
dc.subjectproton transporten
dc.subjectironen
dc.subjectnitric oxideen
dc.subjectSpectroscopy, Fourier Transform Infrareden
dc.subjectRaman spectrometryen
dc.subjecthemeen
dc.subjectmyoglobinen
dc.subjectNitritesen
dc.subjectSpectrum Analysis, Ramanen
dc.subjectElectron Transport Complex IVen
dc.subjectPseudomonas stutzerien
dc.subjectcytochrome c oxidaseen
dc.subjectoxidoreductaseen
dc.subjectnitriteen
dc.subjectascorbic aciden
dc.subjectcbb3 oxidaseen
dc.subjectdithioniteen
dc.subjectnitric oxide reductaseen
dc.subjectnitrous oxideen
dc.titleProbing the nitrite and nitric oxide reductase activity of cbb3 oxidase: Resonance Raman detection of a six-coordinate ferrous heme-nitrosyl species in the binuclear b3/CuB centeren
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1039/c5cc06802a
dc.description.volume51
dc.description.issue98
dc.description.startingpage17398
dc.description.endingpage17401
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :2</p>en
dc.source.abbreviationChem.Commun.en
dc.contributor.orcidPinakoulaki, Eftychia [0000-0003-3320-6112]
dc.gnosis.orcid0000-0003-3320-6112


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