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Magnetic "Molecular Oligomers" Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragment

dc.contributor.authorManoli, Mariaen
dc.contributor.authorAlexandrou, Sofiaen
dc.contributor.authorPham, L.en
dc.contributor.authorLorusso, G.en
dc.contributor.authorWernsdorfer, W.en
dc.contributor.authorEvangelisti, M.en
dc.contributor.authorChristou, Georgeen
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.creatorManoli, Mariaen
dc.creatorAlexandrou, Sofiaen
dc.creatorPham, L.en
dc.creatorLorusso, G.en
dc.creatorWernsdorfer, W.en
dc.creatorEvangelisti, M.en
dc.creatorChristou, Georgeen
dc.creatorTasiopoulos, Anastasios J.en
dc.date.accessioned2019-11-21T06:21:19Z
dc.date.available2019-11-21T06:21:19Z
dc.date.issued2016
dc.identifier.issn1433-7851
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55822
dc.description.abstractTwo nanosized Mn49 and Mn25Na4 clusters based on analogues of the high-spin (S=22) [MnIII 6MnII 4(μ4-O)4]18+ supertetrahedral core are reported. Mn49 and Mn25Na4 complexes consist of eight and four decametallic supertetrahedral subunits, respectively, display high virtual symmetry (Oh), and are unique examples of clusters based on a large number of tightly linked high nuclearity magnetic units. The complexes also have large spin ground-state values (Mn49: S=61/2en
dc.description.abstractMn25Na4: S=51/2) with the Mn49 cluster displaying single-molecule magnet (SMM) behavior and being the second largest reported homometallic SMM. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA.en
dc.sourceAngewandte Chemie - International Editionen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84958101839&doi=10.1002%2fanie.201509461&partnerID=40&md5=e6da24d82721e5901fdaaaae08eaecaa
dc.subjectManganese compoundsen
dc.subjectMagnetismen
dc.subjectMoleculesen
dc.subjectmanganeseen
dc.subjectMagnetsen
dc.subjectSingle-molecule magneten
dc.subjectSodiumen
dc.subjectGround stateen
dc.subjectmagnetic propertiesen
dc.subjectcluster compoundsen
dc.subjectHigh spinsen
dc.subjectLarge spinen
dc.subjectNuclearityen
dc.subjectO ligandsen
dc.subjectsingle-molecule magnetsen
dc.titleMagnetic "Molecular Oligomers" Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragmenten
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1002/anie.201509461
dc.description.volume55
dc.description.issue2
dc.description.startingpage679
dc.description.endingpage684
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :13</p>en
dc.source.abbreviationAngew.Chem.Int.Ed.en
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.gnosis.orcid0000-0002-4804-3822


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