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dc.contributor.authorManos, Manolis J.en
dc.contributor.authorKyprianidou, Eleni J.en
dc.contributor.authorPapaefstathìou, Giannis S.en
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.creatorManos, Manolis J.en
dc.creatorKyprianidou, Eleni J.en
dc.creatorPapaefstathìou, Giannis S.en
dc.creatorTasiopoulos, Anastasios J.en
dc.date.accessioned2019-11-21T06:21:21Z
dc.date.available2019-11-21T06:21:21Z
dc.date.issued2012
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55828
dc.description.abstractSingle-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or tune the properties of the materials via the postsynthetic introduction of suitable guest molecules or organic functional groups into their structures. Here, we describe UCY-2, a new flexible Nd 3+ metal-organic framework (MOF), which exhibits a unique capability to undergo a plethora of SCSC transformations with some of them being very uncommon. These structural alterations involve the replacement of coordinating solvent molecules of UCY-2 by terminally ligating solvents and organic ligands with multiple functional groups including -OH, -SH, -NH-, and -NH 2 or their combinations, chelating ligands, anions, and two different organic compounds. The SCSC coordinating solvent exchange is thus demonstrated as a powerful method for the functionalization of MOFs. © 2012 American Chemical Society.en
dc.sourceInorganic chemistryen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84861932275&doi=10.1021%2fic3005085&partnerID=40&md5=067aac319222d5a40833cd097a323f43
dc.subjectarticleen
dc.subjectchemistryen
dc.subjectcrystallizationen
dc.subjectchemical structureen
dc.subjectX ray crystallographyen
dc.subjectLigandsen
dc.subjectliganden
dc.subjectCoordination Complexesen
dc.subjectcoordination compounden
dc.subjectModels, Molecularen
dc.subjectCrystallography, X-Rayen
dc.subjectsolventen
dc.subjectSolventsen
dc.subjectneodymiumen
dc.titleInsertion of functional groups into a Nd 3+ metal-organic framework via single-crystal-to-single-crystal coordinating solvent exchangeen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ic3005085
dc.description.volume51
dc.description.issue11
dc.description.startingpage6308
dc.description.endingpage6314
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :32</p>en
dc.source.abbreviationInorg.Chem.en
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.contributor.orcidPapaefstathìou, Giannis S. [0000-0001-5514-6371]
dc.gnosis.orcid0000-0002-4804-3822
dc.gnosis.orcid0000-0001-5514-6371


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