dc.contributor.author | Stavrou, Ioannis J. | en |
dc.contributor.author | Moore, L. | en |
dc.contributor.author | Fernand, V. E. | en |
dc.contributor.author | Kapnissi‐Christodoulou, Constantina P. | en |
dc.contributor.author | Warner, I. M. | en |
dc.creator | Stavrou, Ioannis J. | en |
dc.creator | Moore, L. | en |
dc.creator | Fernand, V. E. | en |
dc.creator | Kapnissi‐Christodoulou, Constantina P. | en |
dc.creator | Warner, I. M. | en |
dc.date.accessioned | 2019-11-21T06:22:58Z | |
dc.date.available | 2019-11-21T06:22:58Z | |
dc.date.issued | 2013 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56160 | |
dc.description.abstract | In this study, the dissolution of polysaccharides into an ionic liquid was investigated and applied as a coating onto the capillary walls of a fused-silica capillary in open-tubular CEC. The coating was evaluated by examining the chiral separation of two analytes (thiopental, sotalol) with three cellulose derivatives (cellulose acetate, cellulose acetate phthalate, and cellulose acetate butyrate). Baseline separation of thiopental enantiomers was achieved by use of each polysaccharide coating (Rs: 7.0, 8.1, 7.1), while sotalol provided partial resolution (Rs: 0.7, 1.0, 0.9). In addition, reproducibility of the cellulose-coated capillaries was evaluated by estimating the run-to-run and capillary-to-capillary RSD values of the EOF. Both stability and reproducibility were very good with RSD values of less than 7%. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | en |
dc.source | Electrophoresis | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84877808624&doi=10.1002%2felps.201200563&partnerID=40&md5=053cdc63f6d6a68d5e591b17122a6391 | |
dc.subject | article | en |
dc.subject | controlled study | en |
dc.subject | unclassified drug | en |
dc.subject | structure analysis | en |
dc.subject | concentration (parameters) | en |
dc.subject | process optimization | en |
dc.subject | cellulose acetate | en |
dc.subject | material coating | en |
dc.subject | fluorescence microscopy | en |
dc.subject | Stereoisomerism | en |
dc.subject | dissolution | en |
dc.subject | chirality | en |
dc.subject | enantiomer | en |
dc.subject | capillary electrochromatography | en |
dc.subject | phase separation | en |
dc.subject | temperature measurement | en |
dc.subject | sotalol | en |
dc.subject | acetic acid derivative | en |
dc.subject | Chiral separation | en |
dc.subject | Imidazoles | en |
dc.subject | Ionic Liquids | en |
dc.subject | 1 butyl 3 methylimidazolium acetate | en |
dc.subject | Adrenergic beta-Antagonists | en |
dc.subject | Anesthetics, Intravenous | en |
dc.subject | Butylmethylimidazolium acetate | en |
dc.subject | Capillary electrochromatography cellulose | en |
dc.subject | cellaburate | en |
dc.subject | cellacefate | en |
dc.subject | Cellulose | en |
dc.subject | hydroxyl group | en |
dc.subject | Ionic liquid | en |
dc.subject | open tubular capillary electrochromatography | en |
dc.subject | Polysaccharide | en |
dc.subject | residue analysis | en |
dc.subject | Silicon Dioxide | en |
dc.subject | thiopental | en |
dc.title | Facile preparation of polysaccharide-coated capillaries using a room temperature ionic liquid for chiral separations | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1002/elps.201200563 | |
dc.description.volume | 34 | |
dc.description.issue | 9-10 | |
dc.description.startingpage | 1334 | |
dc.description.endingpage | 1338 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :12</p> | en |
dc.source.abbreviation | Electrophoresis | en |
dc.contributor.orcid | Kapnissi‐Christodoulou, Constantina P. [0000-0003-3755-1052] | |
dc.contributor.orcid | Stavrou, Ioannis J. [0000-0002-9780-4333] | |
dc.gnosis.orcid | 0000-0003-3755-1052 | |
dc.gnosis.orcid | 0000-0002-9780-4333 | |