Mechanism for extrusion instabilities in polymer melts

Abstract

A mechanism for explaining some of the instabilities observed during the extrusion of polymer melts is further explored. This is based on the combination of non-monotonic slip and elasticity, which permits the existence of periodic solutions in viscometric flows. The time-dependent, incompressible, one-dimensional plane Poiseuine flow of an Oldroyd-B fluid with slip along the wall is studied using a nonmonotonic slip equation relating the shear stress to the velocity at the wall. The stability of the steady-state solutions to one-dimensional perturbations at fixed volumetric flow rate is analyzed by means of a linear stability analysis and finite element calculations. Self-sustained periodic oscillations of the pressure gradient are obtained when an unstable steady-state is perturbed, in direct analogy with experimental observations.