Browsing by Author "Moushi, Eleni E."
Now showing items 21-38 of 38
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A missing oxidation-state level in the family of polyoxo(azide)octadecavanadate(IV/V) clusters: Synthesis, structure and antitumoural properties of [VIV11VV7O44(N3)]10 - In a sodium containing-3D architecture
Roubatis, Leonidas; Anastasiadis, Nikolaos C.; Paratriantafyllopoulou, C.; Moushi, Eleni E.; Tasiopoulos, Anastasios J.; Karkabounas, Spyridon Ch; Veltsistas, Panayotis Th; Perlepes, Spyros P.; Evangelou, Angelos M. (2016)The missing VIV11VV7 oxidation-state member of the polyoxooctadecavanadate(IV/V) - azide family of inorganic host-guest systems has been incorporated in a NaI-containing 3D architecture
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A Mn 17 octahedron with a giant ground-state spin: Occurrence in discrete Form and as Multidimensional coordination polymers
Moushi, Eleni E.; Stamatatos, Theocharis C.; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2009)A [Mn lll 11Mn ll 6(μ 4-O) 8(μ 3-L) 4] 25+ (L = N 3 - or OCN -) octahedral unit is reported, occurring within 1D (1)∞ and 2D (2)∞ coordination polymers, as well as the corresponding 0D discrete cluster 3. It possesses a ...
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A Mn 36Ni 4 'loop-of-loops-and-supertetrahedra' aggregate possessing a high S T = 26 ± 1 spin ground state
Charalambous, Maria; Moushi, Eleni E.; Papatriantafyllopoulou, Constantina; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2012)The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a Mn III 28Mn II 8Ni II 4 molecular aggregate which consists of two Mn III 8Ni 2 loops and two Mn III 6Mn II 4 supertetrahedral units and ...
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[Mn14] “Structural Analogues” of Well-Known [Mn12] Single-Molecule Magnets
Charalambous, Maria; Moushi, Eleni E.; Nguyen, Tu N.; Mowson, Andrew M.; Christou, George; Tasiopoulos, Anastasios J. (2018)A new family of tetradecanuclear Mn clusters [MnIII10MnIV4(µ3-O)12(EtCO2)12(pd)4(EtOH)4(py)4](ClO4)2 (1), [MnIII10MnIV4(µ3-O)12(EtCO2)12(mpd)4(EtOH)2(H2O)2(py)4](ClO4)2 (2), and [MnIII10MnIV4(µ3-O)12(MeCO2)10(pic)4(pd)4(pdH2)4] ...
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A Mn15 single-molecule magnet consisting of a supertetrahedron incorporated in a loop
Moushi, Eleni E.; Masello, A.; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2010)Two new Mn15 clusters consisting of a supertetrahedron which is incorporated in a loop are reported. The reactions of [Mn(O2CEt) 2]·2H2O with the diols 1,3-propanediol (H 2pd) or 2-methyl-1,3-propanediol (H2mpd) in the ...
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A new family of octanuclear Mn complexes with a rod-like topology
Moushi, Eleni E.; Stamatatos, Theocharis C.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2009)Three new octanuclear compounds were prepared from reactions of [Mn(O2CR)2]·2H2O (R = Et or Ph) with the diols 1,3-propanediol (pdH2) or 2-methyl-1,3-propanediol (mpdH2) in the presence of NaN3. All three compounds ...
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New Zn 2+ metal organic frameworks with unique network topologies from the combination of trimesic acid and amino-alcohols
Manos, Manolis J.; Moushi, Eleni E.; Papaefstathìou, Giannis S.; Tasiopoulos, Anastasios J. (2012)A series of new Zn 2+-trimesate (btc 3-) metal organic frameworks (MOFs) has been isolated in the presence of various amino-alcohols under solvothermal conditions. Thus, the reaction of ZnCl 2 with trimesic acid (H 3btc) ...
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One-pot regioselective synthesis and X-ray crystal structure of a stable [60]fullerene trisadduct with the eedge,eface,trans-1 addition pattern
Riala, Maria; Markoulides, Marios Savva; Moushi, Eleni E.; Chronakis, Nikos (2011)The Bingel functionalisation of C60 with a structurally novel tether equipped with three reactive malonate groups afforded a C 2v-symmetrical eedge,eface,trans-1 trisadduct in a complete regioselective manner and in an ...
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Self-Assembled Giant Vesicles Formed by Type I [3:3]-Hexakis Adducts of C60 Equipped with Enantiomerically Pure cyclo-Monomalonate Addends
Ioannou, Charalambos P.; Ioannou, Georgios I.; Moushi, Eleni E.; Velonia, Kelly; Chronakis, Nikos (2015)An efficient route for the synthesis of two amphiphilic type I [3:3]-hexakis adducts of C60 equipped with enantiopure cyclo-monomalonate addends was explored. Studies on their self-assembling behavior by TEM and SEM revealed ...
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Single-molecule magnets: A family of MnIII/CeIV complexes with a [Mn8CeO8]12+ core
Mishra, Abhudaya; Tasiopoulos, Anastasios J.; Wernsdorfer, W.; Moushi, Eleni E.; Moulton, B.; Zaworotko, M. J.; Abboud, K. A.; Christou, George (2008)Four heterometallic, enneanuclear Mn8Ce clusters [Mn 8CeO8(O2CMe)12(H2O) 4] (4), [Mn8CeO8(O2CMe) 12(py)4] (5), [Mn8CeO8(O 2CPh)12(MeCN)4] [Mn8CeO 8(O2CPh)12(dioxane)4] (6), and [Mn8CeO8(O2CCHPh2) 12(H2O)4] (7) have been ...
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Solvent-dependent access to mono- and dinuclear copper(II) assemblies based on a flexible imidazole ligand
Kitos, Alexandros A.; Moushi, Eleni E.; Manos, Manolis J.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Perlepes, Spyros P.; Nastopoulos, Vassilios (2016)Seven copper(ii) complexes with the less bulky (compared to bis-phenyl-substituted imidazoles used in our previous studies) monodentate 2-phenylimidazole (LH) ligand have been prepared from the general CuII/X-/LH (X- = ...
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Supramolecular features in the engineering of 3d metal complexes with phenyl-substituted imidazoles as ligands: the case of copper(II)
Kounavi, Konstantina A.; Kitos, Alexandros A.; Moushi, Eleni E.; Manos, Manolis J.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Perlepes, Spyros P.; Nastopoulos, Vassilios (2015)With the aim of recording and assessing the role and impact of various non-covalent interactions activated during the self-assembly process of 3d metal complexes with organic ligands, the synthesis and X-ray characterization ...
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Supramolecular features in the engineering of 3d metal complexes with phenyl-substituted imidazoles as ligands: the case of copper(ii)1
Kounavi, Konstantina A.; Kitos, Alexandros A.; Moushi, Eleni E.; Manos, Manolis J.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Perlepes, Spyros P.; Nastopoulos, Vassilios (2015)
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Supramolecular patterns of cationic and neutral Ni(ii) complexes from the interplay of hydrogen-bonding, stacking interactions and metal-coordination motifs
Kounavi, Konstantina A.; Moushi, Eleni E.; Manos, Manolis J.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios (2012)In an effort to explore the way in which the chemical subunits of crystal structures of transition metal complexes are put together in periodic ordered arrays in the solid state via noncovalent interactions, an investigation ...
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Synthesis and characterization of a linear [Mn3(O 2CMe)4(py)8]2+ complex
Tasiopoulos, Anastasios J.; Moushi, Eleni E.; Kizas, Christos M.; Nastopoulos, Vassilios (2010)Two new compounds that consist of the linear trinuclear manganese(II) cation [Mn3(O2CMe)4(py)8] 2+ cocrystallizing with different counteranions (I3 -, [1]
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Synthesis and structural characterization of a metal cluster and a coordination polymer based on the [Mn6(μ4-O) 2]10+ Unit
Manos, Manolis J.; Moushi, Eleni E.; Tasiopoulos, Anastasios J. (2010)A new 1-D coordination polymer { [Mn6O2(O 2CMe)10 (H2O)4] 2.5 H 2O}λ (1 2.5 H2O) and the cluster [Mn 6O2(O2(O2CPh) 10(py) 2(MeCN)(H2O)] 2MeCN (2 2MeCN) are reported. Both compounds were synthesized by room temperature ...
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A systematic evaluation of the interplay of weak and strong supramolecular interactions in a series of Co(II) and Zn(II) complexes tuned by ligand modification
Kounavi, Konstantina A.; Manos, Manolis J.; Moushi, Eleni E.; Kitos, Alexandros A.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios (2012)A systematic investigation on a designed series of 21 transition metal complexes has been carried out with the intention to explore and assess the relative strength and the way in which intermolecular interactions, namely, ...
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Two new coordination polymers containing the triangular [Mn3O(O2CR)6]0/+ units
Zartilas, Sotiris M.; Moushi, Eleni E.; Nastopoulos, Vassilios; Boudalis, Athanassios K.; Tasiopoulos, Anastasios J. (2008)The preparation and crystal structures of two linear chain compounds of oxo-centered triangular Mn clusters are reported. {[Mn4O(O2CMe)8(py)] · 2MeCN}∞ (1 · 2MeCN)∞ was formed when a concentrated solution of [Mn3O(O2CMe)6(py)3] ...