A Mn 36Ni 4 'loop-of-loops-and-supertetrahedra' aggregate possessing a high S T = 26 ± 1 spin ground state
Date
2012Author
Charalambous, MariaMoushi, Eleni E.
Papatriantafyllopoulou, Constantina
Wernsdorfer, W.
Nastopoulos, Vassilios
Christou, George
Tasiopoulos, Anastasios J.
ISSN
1359-7345Source
Chemical CommunicationsVolume
48Issue
44Pages
5410-5412Google Scholar check
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The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a Mn III 28Mn II 8Ni II 4 molecular aggregate which consists of two Mn III 8Ni 2 loops and two Mn III 6Mn II 4 supertetrahedral units and displays a high ground spin state value S T = 26 ± 1. © 2012 The Royal Society of Chemistry.