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Browsing by Subject "Copolymerization"

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    • Article  

      Alternating amphiphilic multiblock copolymers: Controlled synthesis via RAFT polymerization and aqueous solution characterization 

      Hadjiantoniou, N. A.; Krasia-Christoforou, T.; Loizou, E.; Porcar, L.; Patrickios, C. S. (2010)
      Four linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate (DMAEMA, hydrophilic) and methyl methacrylate (MMA, hydrophobic), bearing from two to five blocks, were synthesized using reversible ...

    • Article  

      Alternating amphiphilic multiblock copolymers: Controlled synthesis via RAFT polymerization and aqueous solution characterization 

      Hadjiantoniou, Natalie A.; Krasia‐Christoforou, Theodora; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2010)
      Four linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate (DMAEMA, hydrophilic) and methyl methacrylate (MMA, hydrophobic), bearing from two to five blocks, were synthesized using reversible ...

    • Article  

      Controlled production of ZnO nanoparticles from zinc glycerolate in a sol-gel silica matrix 

      Moleski, R.; Leontidis, Epameinondas; Krumeich, F. (2006)
      The controlled production of ZnO nanoparticles within an amorphous silica matrix is achieved using a new methodology consisting of four stages. First, precursor zinc glycerolate nanoparticles are produced within reversed ...

    • Article  

      Degradable amphiphilic end-linked conetworks with aqueous degradation rates determined by polymer topology 

      Rikkou-Kalourkoti, Maria D.; Loizou, Elena; Porcar, L.; Butler, P.; Patrickios, Costas S. (2009)
      Degradable amphiphilic conetworks, based on end-linked amphiphilic ABA triblock copolymers with a labile fragment in the middle, were synthesized by sequential group transfer polymerization (GTP) of monomers and cross-linker, ...

    • Article  

      Di(n-butyl) itaconate end-functionalized polymers: Synthesis by group transfer polymerization and solution characterization 

      Kassi, Eleni; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2011)
      In this study we present our efforts to homo- and co-polymerize, using group transfer polymerization (GTP), a dialkyl diester of itaconic acid, a naturally-derived unsaturated dicarboxylic acid. The monomer employed, ...

    • Article  

      End-linked amphiphilic polymer conetworks: synthesis by sequential atom transfer radical polymerization and swelling characterization 

      Rikkou-Kalourkoti, Maria D.; Kolokasi, Maria; Matyjaszewski, K.; Patrickios, Costas S. (2010)
      Conetworks based on end-linked homopolymers and amphophilic gradient copolymers were synthesized by the atom transfer radical polymerization (ATRP) of 2-(dimethylamino)ethyl methaerylate (DMAEMA, hydrophilic monomer), ...

    • Article  

      End-linked semifluorinated amphiphilic polymer conetworks: Synthesis by sequential reversible addition - Fragmentation chain transfer polymerization and characterization 

      Pafiti, Kyriaki S.; Loizou, Elena; Patrickios, Costas S.; Porcar, L. (2010)
      One-pot, sequential reversible addition - fragmentation chain transfer (RAFT) polymerization was employed for the preparation of five end-linked semifluorinated amphiphilic polymer conetworks based on 2,2,2-trifluoroethyl ...

    • Article  

      Poly(ethylene glycol)-based amphiphilic model conetworks: Synthesis by RAFT polymerization and characterization 

      Achilleos, Mariliz; Legge, T. M.; Perrier, S.; Patrickios, Costas S. (2008)
      Polyethylene glycol) (PEG)-containing quasi-model amphiphilic polymer conetworks (APCNs) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization using α,ω-bis(2-cyanoprop-2-yl dithiobenzoate)-PEG ...

    • Article  

      Preparation and nonlinear optical response of novel palladium-containing micellar nanohybrids 

      Iliopoulos, K.; Chatzikyriakos, G.; Demetriou, M.; Krasia-Christoforou, T.; Couris, S. (2011)
      The synthesis and characterization of novel micellar nanohybrids with controllable sizes consisting of palladium nanosized core and covered by well-defined poly(lauryl methacrylate)-block-poly(2-(acetoacetoxy)ethyl ...

    • Article  

      Reversible hydrogels from amphiphilic polyelectrolyte model multiblock copolymers: The importance of macromolecular topology 

      Popescu, M. -T; Athanasoulias, I.; Tsitsilianis, C.; Hadjiantoniou, Natalie A.; Patrickios, Costas S. (2010)
      The association ability of model amphiphilic polyelectrolytes with multi-block architecture, i.e. ABA, BABAB, ABABABA and BABABABAB (A hydrophobic, B polyelectrolyte block) was studied in aqueous media. The gelation ...

    • Article  

      Structural characterization of amphiphilic polymer conetworks end-linked with the optimal amount of cross-linker 

      Rikkou-Kalourkoti, Maria D.; Loizou, Elena; Patrickios, Costas S.; Porcar, L. (2010)
      Amphiphilic polymer conetworks were synthesized by the end-linking of ABA triblock copolymers using optimal (minimal) amount of cross-linker in pursuit of nanoscale phase separated materials with a long-range order. ...

    • Article  

      Superparamagnetic hybrid micelles, based on iron oxide nanoparticles and well-defined diblock copolymers possessing β-ketoester functionalities 

      Papaphilippou, P.; Loizou, L.; Popa, N. C.; Han, A.; Vekas, L.; Odysseos, A.; Krasia-Christoforou, T. (2009)
      The quality of surface coating of magnetic nanoparticles destined as nanoprobes in clinical applications is of utmost significance for their colloidal stability and biocompatibility. A novel approach for the fabrication ...

    • Article  

      Synthesis and characterization of amphiphilic multiblock copolymers: Effect of the number of blocks on micellization 

      Hadjiantoniou, Natalie A.; Triftaridou, Aggeliki I.; Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2009)
      Five linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate ("D") and methyl methacrylate ("M"), bearing from two to six blocks, were synthesized using sequential group transfer polymerization. ...

    • Article  

      Synthesis and characterization of water-dispersible, superparamagnetic single-wall carbon nanotubes decorated with iron oxide nanoparticles and well-defined chelating diblock copolymers 

      Papaphilippou, P.; Turcu, R.; Krasia-Christoforou, T. (2011)
      A novel approach for the fabrication of magneto-active carbon nanotubes (CNTs) stabilized in aqueous media, involving the combination of carboxylated single-wall carbon nanotubes (SWCNTs) with a new class of methacrylate-based ...

    • Article  

      Synthesis and characterization of well-defined block and statistical copolymers based on lauryl methacrylate and 2-(acetoacetoxy)ethyl methacrylate using RAFT-controlled radical polymerization 

      Demetriou, M.; Krasia-Christoforou, T. (2008)
      Four well-defined diblock copolymers and one statistical copolymer based on lauryl methacrylate (LauMA) and 2-(acetoacetoxy)ethyl methacrylate (AEMA) were prepared using reversible addition-fragmentation chain transfer ...

    • Article  

      Synthesis, characterization, and evaluation as transfection reagents of ampholytic star copolymers: Effect of star architecture 

      Georgiou, Theoni K.; Phylactou, Leonidas A.; Patrickios, Costas S. (2006)
      Five star polymers based on the positively ionizable hydrophilic 2-(dimethylamino)ethyl methacrylate (DMAEMA) and the hydrophobic but hydrolyzable tetrahydropyranyl methacrylate (THPMA) were prepared by group-transfer ...

    • Article  

      Synthesis, characterization, and modeling of cationic amphiphilic model hydrogels: Effects of polymer composition and architecture 

      Triftaridou, Aggeliki I.; Hadjiyannakou, Stella C.; Vamvakaki, Maria; Patrickios, Costas S. (2002)
      Group transfer polymerization (GTP) was used for the preparation of eight amphiphilic networks based on 2-(dimethylamino)ethyl methacrylate (DMAEMA) and methyl methacrylate (MMA). Seven of the networks had linear segments ...

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