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Browsing by Subject "Copolymers"

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Now showing items 1-20 of 34

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    • Article  

      2-(2,3,4,5,6-Pentafluorophenyl)-1H-benzo[d]imidazole, a fluorine-rich building block for the preparation of conjugated polymer donors for organic solar cell applications 

      Neophytou, Marios; Ioannidou, Heraklidia A.; Ioannou, Theodosia A.; Chochos, Christos L.; Economopoulos, Solon P.; Koutentis, Panayiotis Andreas; Itskos, Grigorios; Choulis, Stelios A. (2012)
      We have introduced the pentafluorophenyl substituted benzimidazole as a building block of conjugated polymers for optoelectronic applications. We present the synthesis of a copolymer bearing fluorene as the comonomer. A ...

    • Article  

      Amphiphilic diblock and ABC triblock methacrylate copolymers: Synthesis and aqueous solution characterization 

      Triftaridou, Aggeliki I.; Vamvakaki, Maria; Patrickios, Costas S. (2002)
      Three isomeric, linear, equimolar, amphiphilic ABC triblock copolymers comprising methyl methacrylate (MMA, nonionic hydrophobic), 2-(dimethylamino)ethyl methacrylate, (DMAEMA, ionizable hydrophilic) and hexa(ethylene ...

    • Article  

      Amphiphilic model conetworks based on cross-linked star copolymers of benzyl methacrylate and 2-(dimenthylamino)ethyl methacrylate: Synthesis, characterization, and DNA adsorption studies 

      Achilleos, Demetra S.; Georgiou, Theoni K.; Patrickios, Costas S. (2006)
      Six amphiphilic model conetworks of a new structure, that of cross-linked "in-out" star copolymers, were synthesized by the group transfer polymerization (GTP) of the hydrophobic monomer benzyl methacrylate (BzMA) and the ...

    • Article  

      Amphiphilic networks based on cross-linked star polymers: A small-angle neutron scattering study 

      Vamvakaki, Maria; Patrickios, Costas S.; Lindner, P.; Gradzielski, M. (2007)
      Four different polymer model networks of identical molecular architecture based on cross-linked stars (CLSs) were investigated by small-angle neutron scattering (SANS). One of the model networks was a hydrophilic homopolymer ...

    • Article  

      Di(n-butyl) itaconate end-functionalized polymers: Synthesis by group transfer polymerization and solution characterization 

      Kassi, Eleni; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2011)
      In this study we present our efforts to homo- and co-polymerize, using group transfer polymerization (GTP), a dialkyl diester of itaconic acid, a naturally-derived unsaturated dicarboxylic acid. The monomer employed, ...

    • Article  

      Excitation dynamics of a low bandgap silicon-bridged dithiophene copolymer and its composites with fullerenes 

      Othonos, Andreas S.; Itskos, Grigorios; Neophytou, Marios; Choulis, Stelios A. (2012)
      We report on excitation dynamics in pristine and bulk heterojunction films of the low bandgap silicon-bridged dithiophene copolymer poly[(4,4′-bis(2- ethylhexyl)dithieno[3,2-b:2′, 3′-d]silole)-2,6-diyl-alt-(4,7-bis(2- ...

    • Article  

      Fabrication and characterization of magnetoresponsive electrospun nanocomposite membranes based on methacrylic random copolymers and magnetite nanoparticles 

      Savva, I.; Krekos, G.; Taculescu, A.; Marinica, O.; Vekas, L.; Krasia-Christoforou, T. (2012)
      Magnetoresponsive polymer-based fibrous nanocomposites belonging to the broad category of stimuli-responsive materials, is a relatively new class of soft composite materials, consisting of magnetic nanoparticles embedded ...

    • Article  

      Identifying potential candidates for donor-acceptor copolymers on a series of 4H-1,2,6-thiadiazines: An electrochemical approach 

      Economopoulos, Solon P.; Koutentis, Panayiotis Andreas; Ioannidou, Heraklidia A.; Choulis, Stelios A. (2013)
      A series of synthesized small organic molecules based on the 4H-1,2,6-thiadiazine moiety are studied using electrochemistry, to probe their potential as comonomer building blocks for solar-absorbing polymers for organic ...

    • Article  

      In vivo imaging of quantum dots encapsulated in phospholipid micelles 

      Dubertret, B.; Skourides, Paris A.; Norris, D. J.; Brivanlou, A. H.; Libchaber, A.; Noireaux, V. (2002)
      Fluorescent semiconductor nanocrystals (quantum dots) have the potential to revolutionize biological imaging, but their use has been limited by difficulties in obtaining nanocrystals that are biocompatible. To address this ...

    • Article  

      An innovative synthesis approach toward the preparation of structurally defined multiresponsive polymer (co)networks 

      Achilleos, M.; Demetriou, M.; Marinica, O.; Vekas, L.; Krasia-Christoforou, T. (2014)
      A new and facile synthesis approach employed for the fabrication of multiresponsive polymer conetworks characterized by predefined architecture and composition is described for the first time. The presented methodology ...

    • Article  

      Mechanical properties of structurally-defined magnetoactive polymer (co)networks 

      Mpekris, F.; Achilleos, M.; Vasile, E.; Vasile, E.; Krasia-Christoforou, T.; Stylianopoulos, T. (2015)
      The mechanical properties of structurally-defined magnetoactive polymer (co)networks synthesized from well-defined poly(2-dimethylamino)ethyl methacrylate (poly(DMAEMA)) homopolymers and diblock copolymers of poly(DMAEMA) ...

    • Article  

      Poly(ethylene glycol)-based amphiphilic model conetworks: Synthesis by RAFT polymerization and characterization 

      Achilleos, Mariliz; Legge, T. M.; Perrier, S.; Patrickios, Costas S. (2008)
      Polyethylene glycol) (PEG)-containing quasi-model amphiphilic polymer conetworks (APCNs) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization using α,ω-bis(2-cyanoprop-2-yl dithiobenzoate)-PEG ...

    • Article  

      Reversible hydrogels from amphiphilic polyelectrolyte model multiblock copolymers: The importance of macromolecular topology 

      Popescu, M. -T; Athanasoulias, I.; Tsitsilianis, C.; Hadjiantoniou, Natalie A.; Patrickios, Costas S. (2010)
      The association ability of model amphiphilic polyelectrolytes with multi-block architecture, i.e. ABA, BABAB, ABABABA and BABABABAB (A hydrophobic, B polyelectrolyte block) was studied in aqueous media. The gelation ...

    • Article  

      Stimuli-Responsive amphiphilic polyelectrolyte heptablock copolymer physical hydrogels: An unusual ph-response 

      Popescu, M. -T; Tsitsilianis, C.; Papadakis, Christine M.; Adelsberger, J.; Balog, Sándor; Busch, P.; Hadjiantoniou, Natalie A.; Patrickios, Costas S. (2012)
      An amphiphilic cationic polyelectrolyte based on poly[2-(dimethylamino) ethyl methacrylate] (polyDMA) and poly(n-butyl methacrylate) (polyBuMA) with a BuMA-DMA-BuMA-DMA-BuMA-DMA-BuMA heptablock copolymer architecture was ...

    • Article  

      Synthesis and aqueous solution characterization of amphiphilic diblock copolymers containing carbazole 

      Krasia-Christoforou, T.; Patrickios, C. S. (2002)
      A series of near-monodisperse diblock copolymers of 2-(N-carbazolyl)ethyl methacrylate and 2-(dimethylamino)ethyl methacrylate (DMAEMA) of relatively low molecular weights (2600-24,000 g mol-1) were synthesized by group ...

    • Article  

      Synthesis and aqueous solution characterization of amphiphilic diblock copolymers containing carbazole 

      Krasia‐Christoforou, Theodora; Patrickios, Costas S. (2002)
      A series of near-monodisperse diblock copolymers of 2-(N-carbazolyl)ethyl methacrylate and 2-(dimethylamino)ethyl methacrylate (DMAEMA) of relatively low molecular weights (2600-24,000 g mol-1) were synthesized by group ...

    • Article  

      Synthesis and aqueous solution characterization of novel diblock polyampholytes containing imidazole 

      Hadjikallis, G.; Hadjiyannakou, Stella C.; Vamvakaki, Maria; Patrickios, Costas S. (2002)
      A series of diblock copolymers of 2-(1-imidazolyl)ethyl methacrylate and tetrahydropyranyl methacrylate (THPMA) were synthesized by group transfer polymerization using propylene carbonate rather than tetrahydrofuran as the ...

    • Article  

      Synthesis and characterization of amphiphilic conetworks based on multiblock copolymers 

      Hadjiantoniou, Natalie A.; Patrickios, Costas S. (2007)
      Model amphiphilic conetworks based on cross-linked block copolymers of the hydrophilic ionizable 2-(dimethylamino)ethyl methacrylate (DMAEMA, 25 nominal units per block) and the hydrophobic n-butyl methacrylate (BuMA, 5 ...

    • Article  

      Synthesis and characterization of amphiphilic multiblock copolymers: Effect of the number of blocks on micellization 

      Hadjiantoniou, Natalie A.; Triftaridou, Aggeliki I.; Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2009)
      Five linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate ("D") and methyl methacrylate ("M"), bearing from two to six blocks, were synthesized using sequential group transfer polymerization. ...

    • Article  

      Synthesis and characterization of amphiphilic star copolymers of 2-(dimethylamino)ethyl methacrylate and methyl methacrylate: Effects of architecture and composition 

      Themistou, Efrosyni; Patrickios, Costas S. (2007)
      Six amphiphilic star copolymers comprising hydrophilic units of 2-(dimethylamino)ethyl methacrylate (DMAEMA) and hydrophobic units of methyl methacrylate (MMA) were prepared by the sequential group transfer polymerization ...

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