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Browsing by Subject "Ethylene glycol"

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    • Article  

      Double Networks Based on Amphiphilic Cross-Linked Star Block Copolymer First Conetworks and Randomly Cross-Linked Hydrophilic Second Networks 

      Rikkou-Kalourkoti, Maria D.; Kitiri, E. N.; Patrickios, Costas S.; Leontidis, Epameinondas; Constantinou, Martha; Constantinides, G.; Zhang, X. K.; Papadakis, Christine M. (2016)
      This study presents the preparation and characterization of double networks (DN) based on a first amphiphilic polymethacrylate conetwork (APCN) and a second polyacrylamide network. The APCN first network comprised ...

    • Article  

      Dynamic Covalent Star Poly(ethylene glycol) Model Hydrogels: A New Platform for Mechanically Robust, Multifunctional Materials 

      Apostolides, Demetris E.; Sakai, T.; Patrickios, Costas S. (2017)
      We develop a new platform of dynamic covalent model polymer networks comprising two types of four-armed star poly(ethylene glycol)s (tetraPEG), one end-functionalized with benzaldehyde groups and the other with ...

    • Article  

      End-linked amphiphilic polymer conetworks: synthesis by sequential atom transfer radical polymerization and swelling characterization 

      Rikkou-Kalourkoti, Maria D.; Kolokasi, Maria; Matyjaszewski, K.; Patrickios, Costas S. (2010)
      Conetworks based on end-linked homopolymers and amphophilic gradient copolymers were synthesized by the atom transfer radical polymerization (ATRP) of 2-(dimethylamino)ethyl methaerylate (DMAEMA, hydrophilic monomer), ...

    • Article  

      End-linked poly[2-(dimethylamino)ethyl methacrylate]-poly(methacrylic acid) polyampholyte conetworks: Synthesis by sequential RAFT polymerization and swelling and SANS characterization 

      Pafiti, Kyriaki S.; Philippou, Zelina; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2011)
      Four well-defined end-linked triblock polyampholyte conetworks composed of positively ionizable 2-(dimethylamino)ethyl methacrylate (DMAEMA) repeating units and negatively ionizable methacrylic acid (MAA) repeating units ...

    • Article  

      End-linked semifluorinated amphiphilic polymer conetworks: Synthesis by sequential reversible addition - Fragmentation chain transfer polymerization and characterization 

      Pafiti, Kyriaki S.; Loizou, Elena; Patrickios, Costas S.; Porcar, L. (2010)
      One-pot, sequential reversible addition - fragmentation chain transfer (RAFT) polymerization was employed for the preparation of five end-linked semifluorinated amphiphilic polymer conetworks based on 2,2,2-trifluoroethyl ...

    • Article  

      Fabrication and characterization of superparamagnetic and thermoresponsive hydrogels based on oleic-acid-coated Fe3O4 nanoparticles, hexa(ethylene glycol) methyl ether methacrylate and 2-(acetoacetoxy)ethyl methacrylate 

      Papaphilippou, P.; Pourgouris, A.; Marinica, O.; Taculescu, A.; Athanasopoulos, G. I.; Vekas, L.; Krasia-Christoforou, T. (2011)
      Stimuli-responsive hydrogel nanocomposites comprised of swollen polymer networks, in which magnetic nanoparticles are embedded, are a relatively new class of "smart" soft materials presenting a significant impact on various ...

    • Article  

      Hydrophilic, cationic large-core star polymers and polymer networks: Synthesis and physicochemical characterization 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2008)
      Group transfer polymerization was used to prepare hydrophilic, cationic large-core star polymers (LCSPs) and networks of 2-(dimethylamino)ethyl methacrylate (DMAEMA) and ethylene glycol dimethacrylate (EGDMA) in a two-step ...

    • Article  

      Multiresponsive polymer conetworks capable of responding to changes in pH, temperature, and magnetic field: Synthesis, characterization, and evaluation of their ability for controlled uptake and release of solutes 

      Papaphilippou, P.; Christodoulou, M.; Marinica, O. M.; Taculescu, A.; Vekas, L.; Chrissafis, K.; Krasia-Christoforou, T. (2012)
      This study deals with the preparation of novel multiresponsive (magnetoresponsive, thermoresponsive and pH-responsive) nanocomposite conetworks consisting of oleic acid-coated magnetite nanoparticles (OA•Fe 3O 4), ...

    • Article  

      Poly(ethylene glycol)-based amphiphilic model conetworks: Synthesis by RAFT polymerization and characterization 

      Achilleos, Mariliz; Legge, T. M.; Perrier, S.; Patrickios, Costas S. (2008)
      Polyethylene glycol) (PEG)-containing quasi-model amphiphilic polymer conetworks (APCNs) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization using α,ω-bis(2-cyanoprop-2-yl dithiobenzoate)-PEG ...

    • Article  

      Semisegmented amphiphilic polymer conetworks: Synthesis and characterization 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2009)
      Semisegmented amphiphilic polymer conetworks (APCNs) based on the hydrophilic monomer 2-(dimethylamino)ethyl methacrylate (DMAEMA), the hydrophobic monomer methyl methacrylate (MMA), and the hydrophobic cross-linker ethylene ...

    • Article  

      Structural characterization of amphiphilic polymer conetworks end-linked with the optimal amount of cross-linker 

      Rikkou-Kalourkoti, Maria D.; Loizou, Elena; Patrickios, Costas S.; Porcar, L. (2010)
      Amphiphilic polymer conetworks were synthesized by the end-linking of ABA triblock copolymers using optimal (minimal) amount of cross-linker in pursuit of nanoscale phase separated materials with a long-range order. ...

    • Article  

      Structure and Magnetic Property Control of Copper Hydroxide Acetate by Non-Classical Crystallization 

      Song, R.; Krasia-Christoforou, T.; Debus, C.; Cölfen, H. (2017)
      Copper hydroxide acetate (CHA), one layered hydroxide compound with tunable magnetism, attracts great interest because of its potential applications in memory devices. However, ferromagnetism for CHA is only demonstrated ...

    • Article  

      Superparamagnetic hybrid micelles, based on iron oxide nanoparticles and well-defined diblock copolymers possessing β-ketoester functionalities 

      Papaphilippou, P.; Loizou, L.; Popa, N. C.; Han, A.; Vekas, L.; Odysseos, A.; Krasia-Christoforou, T. (2009)
      The quality of surface coating of magnetic nanoparticles destined as nanoprobes in clinical applications is of utmost significance for their colloidal stability and biocompatibility. A novel approach for the fabrication ...

    • Article  

      Synthesis and characterization of amphiphilic cationic symmetrical ABCBA pentablock terpolymer networks: Effect of hydrophobic content 

      Triftaridou, Aggeliki I.; Loizou, Elena; Patrickios, Costas S. (2008)
      Group transfer polymerization was employed for the preparation of six amphiphilic terpolymer networks comprising the hydrophilic, pH-responsive 2-(dime-thylamino)ethyl methacrylate (DMAEMA), the neutral hydrophilic methoxy ...

    • Article  

      Synthesis and characterization of large-core star polymers and polymer networks: Effects of arm length and composition of the cross-linking mixture 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2009)
      Large-core star polymers (LCSPs) and polymer networks were prepared using sequential group transfer polymerization (GTP) for the synthesis of linear poly(methyl methacrylate) (polyMMA) arms, followed by their cross-linking ...

    • Article  

      Synthesis and characterization of shell-cross-linked polymer networks and large-core star polymers: Effect of the volume of the cross-linking mixture 

      Kafouris, Demetris; Patrickios, Costas S. (2009)
      Group transfer polymerization and sequential addition of monomer and cross-linker were employed for the preparation of two new polymer structures, one of a polymer network and the other of a star polymer. The synthesis was ...

    • Article  

      Synthesis and characterization of the swelling and mechanical properties of amphiphilic ionizable model co-networks containing n-butyl methacrylate hydrophobic blocks 

      Vamvakaki, Maria; Patrickios, Costas S. (2008)
      Amphiphilic ionizable model co-networks based on near-monodisperse, linear ABA and BAB triblock and statistical copolymers of 2-(dimethylamino)ethyl methacrylate (DMAEMA, hydrophilic ionizable) and n-butyl methacrylate ...

    • Article  

      Synthesis and characterization of water-dispersible, superparamagnetic single-wall carbon nanotubes decorated with iron oxide nanoparticles and well-defined chelating diblock copolymers 

      Papaphilippou, P.; Turcu, R.; Krasia-Christoforou, T. (2011)
      A novel approach for the fabrication of magneto-active carbon nanotubes (CNTs) stabilized in aqueous media, involving the combination of carboxylated single-wall carbon nanotubes (SWCNTs) with a new class of methacrylate-based ...

    • Article  

      Well-defined polymers from biosourced monomers: The case of 2-(methacryloyloxy)ethyl tiglate 

      Kassi, Eleni; Patrickios, Costas S. (2010)
      Tiglic acid esters are naturally derived olefins of pleasant odor but incapable of undergoing free-radical polymerization due to the steric hindrances conferred by the β-methyl group. In an effort to incorporate these green ...

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