Browsing by Subject "Ferric Compounds"
Now showing items 1-5 of 5
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Article
Effects of sol-gel synthesis on 5Fe-15Mn-40Zn-40Ti-O mixed oxide structure and its H2S removal efficiency from industrial gas streams
(2009)A novel Fe-Mn-Zn-Ti-O mixed metal oxide has been developed for efficient low-temperature (25-50°C) removal of H2S from a gas mixture containing 600 ppm H2S, 25 vol% H2, 7.5 vol % CO 2, and 1-3 vol% H2O that simulates typical ...
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Article
The origin of the Fe IV = O intermediates in cytochrome aa 3 oxidase
(2012)The dioxygen reduction mechanism in cytochrome oxidases relies on proton control of the electron transfer events that drive the process. Proton delivery and proton channels in the protein that are relevant to substrate ...
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Article
Pentanuclear complexes with unusual structural topologies from the initial use of two aliphatic amino-alcohol ligands in Fe chemistry
(2012)Five novel pentanuclear Fe 3+ clusters with the aliphatic amino-alcohol ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [Fe 5(μ 3-Ο) 2(L) 4(O 2CR) 7] [L = ap -, R = Ph (1)
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Article
Superparamagnetic hybrid micelles, based on iron oxide nanoparticles and well-defined diblock copolymers possessing β-ketoester functionalities
(2009)The quality of surface coating of magnetic nanoparticles destined as nanoprobes in clinical applications is of utmost significance for their colloidal stability and biocompatibility. A novel approach for the fabrication ...
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Article
Synthesis, characterization, and study of octanuclear iron-oxo clusters containing a redox-active Fe4O4-cubane core
(2008)A one-pot synthetic procedure yields the octanuclear FeIII complexes Fe8(μ4-O)4(μ-pz*) 12X4, where X = Cl and pz* = pyrazolate anion (pz = C3H3N2-) (1), 4-Cl-pz (2), and 4-Me-pz (3) or X = Br and pz* = pz (4). The crystal ...