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Browsing by Subject "Manganese compounds"

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    • Article  

      Effects of sol-gel synthesis on 5Fe-15Mn-40Zn-40Ti-O mixed oxide structure and its H2S removal efficiency from industrial gas streams 

      Polychronopoulou, Kyriaki; Efstathiou, Angelos M. (2009)
      A novel Fe-Mn-Zn-Ti-O mixed metal oxide has been developed for efficient low-temperature (25-50°C) removal of H2S from a gas mixture containing 600 ppm H2S, 25 vol% H2, 7.5 vol % CO 2, and 1-3 vol% H2O that simulates typical ...

    • Article  

      Employment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: MnII2MnIV and MnII 2MnIII6 complexes 

      Stoumpos, Constantinos C.; Stamatatos, Theocharis C.; Sartzi, H.; Roubeau, O.; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Teat, S. J.; Christou, George; Perlepes, Spyros P. (2009)
      The employment of the anion of methyl 2-pyridyl ketone oxime (mpko -) as a tridentate chelating/bridging ligand in manganese chemistry is described. The inorganic anion (Br-, ClO4-) used in the reaction affects the identity ...

    • Article  

      A family of 3D coordination polymers composed of Mn19 magnetic units 

      Moushi, Eleni E.; Stamatatos, Theocharis C.; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2006)
      (Figure Presented) Singles networks: The use of 1,3-propanediol and of 2-methyl-1,3-propanediol in manganese carboxylate chemistry leads to two new 3D coordination polymers with an unprecedented Mn19 repeating unit. The ...

    • Article  

      Inducing single-molecule magnetism in a family of loop-of-loops aggregates: Heterometallic Mn40Na4 clusters and the homometallic Mn44 analogue 

      Moushi, Eleni E.; Lampropoulos, Christos; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2010)
      The syntheses, crystal structures, and magnetic properties of a new family of heterometallic Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of [Mn3O(O 2CMe)6(py)3]•py with 1,3-propanediol ...

    • Article  

      Magnetic "Molecular Oligomers" Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragment 

      Manoli, Maria; Alexandrou, Sofia; Pham, L.; Lorusso, G.; Wernsdorfer, W.; Evangelisti, M.; Christou, George; Tasiopoulos, Anastasios J. (2016)
      Two nanosized Mn49 and Mn25Na4 clusters based on analogues of the high-spin (S=22) [MnIII 6MnII 4(μ4-O)4]18+ supertetrahedral core are reported. Mn49 and Mn25Na4 complexes consist of eight and four decametallic supertetrahedral ...

    • Article  

      Magnetic properties of Fe/AlO x/GaAs(001) structures 

      Vaz, C. A. F.; Ionescu, A.; Trypiniotis, Theodossis; Bland, J. A. C.; Dalgliesh, R. M.; Langridge, S. (2005)
      We report results on the effect of the Al Ox barrier layer on the magnetic moment of Fe using polarized neutron reflection. The sample has nominal composition 25 nm Au5 nm Fe1.3 nm Al Ox GaAs (001). The metal deposition ...

    • Article  

      A Mn15 single-molecule magnet consisting of a supertetrahedron incorporated in a loop 

      Moushi, Eleni E.; Masello, A.; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2010)
      Two new Mn15 clusters consisting of a supertetrahedron which is incorporated in a loop are reported. The reactions of [Mn(O2CEt) 2]·2H2O with the diols 1,3-propanediol (H 2pd) or 2-methyl-1,3-propanediol (H2mpd) in the ...

    • Article  

      A [Mn32] double-decker wheel 

      Manoli, Maria; Inglis, R.; Manos, Manolis J.; Nastopoulos, Vassilios; Wernsdorfer, W.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2011)
      Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example ...

    • Article  

      Preparation and characterization of a cerium(IV)-incorporated manganese oxide OMS-2. Effect of cerium(IV) template on octahedral molecular sieves of manganese oxide and characterization of manganese oxide molecular sieves with cerium(IV) as dopant 

      Hapeshi, Evroula; Theocharis, Charis R. (2008)
      The manganese oxide material K-OMS-2 was synthesized both via a redox reaction between potassium permanganate and manganese nitrate in an acidic medium (nitric acid) under reflux conditions and by the sol-gel reaction ...

    • Article  

      Preparation and characterization of nanoporous ceria containing heteroatoms, with and without a matrix 

      Theocharis, Charis R.; Kyriakou, Georgia; Christophidou, Maria (2005)
      We have been interested in the synthesis and study of porous ceria, because of its importance in several catalytic applications, and notably in automobile exhaust catalysts. The mesoporosity of these solids is susceptible ...

    • Conference Object  

      Reduced-complexity verification for initial-state opacity in modular discrete event systems 

      Saboori, A.; Hadjicostis, Christoforos N. (2010)
      In this paper, we propose and analyze reduced-complexity methodologies for verifying initial-state opacity in modular discrete event systems. Initial-state opacity requires that the membership of the system initial state ...

    • Article  

      A reductive-aggregation route to [Mn12O12(OMe) 2(O2CPh)16(H2O)2] 2- single-molecule magnets related to the [Mn12] family 

      Tasiopoulos, Anastasios J.; Wernsdorfer, W.; Abboud, K. A.; Christou, George (2004)
      Axes of power: Jahn-Teller isomerism (that is, Jahn-Teller distortion along different axes) accounts for the presence of both faster and slower relaxing magnetization dynamics of the title compound (see core structure

    • Article  

      "Squaring the clusters": A Mn III 4Ni II 4 molecular square from nickel(ii)-induced structural transformation of a Mn II/III/IV 12 cage 

      Alexandropoulos, Dimitris I.; Manos, Manolis J.; Papatriantafyllopoulou, Constantina; Mukherjee, S.; Tasiopoulos, Anastasios J.; Perlepes, Spyros P.; Christou, George; Stamatatos, Theocharis C. (2012)
      A Mn III 4Ni II 4 molecular square exhibiting slow magnetization relaxation has been prepared from the reaction of a Mn II 4Mn III 6Mn IV 2 cluster and a simple Ni II source. © The Royal Society of Chemistry 2012.

    • Doctoral Thesis  Open Access

      Νέες δομικές τοπολογίες, υψηλού σπιν ενώσεις και μοριακοί νανομαγνήτες από τη χρήση της 1,3-προπανοδιόλης και παραγωγών της στη χημεία πολυμεταλλικών πλειάδων του μαγγανίου 

      Μούσιη, Ελένη Ε. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2009-01)
      Το θέμα της παρούσας διδακτορικής διατριβής είναι η σύνθεση και ο χαρακτηρισμός νέων πολυπυρηνικών ενώσεων του μαγγανίου με τις αλειφατικές διόλες 1,3-προπανοδιόλη (H2pd), 2-μέθυλ-1,3-προπανοδιόλη (H2mpd), 2-βρώμο-2-νίτρ ...

    • Doctoral Thesis  Open Access

      Σύνθεση μεικτών φάσεων οξειδίου μαγγανίου-δημητρίου και μελέτη του ρόλου του διαλύτη στις επιφανειακές ιδιότητες της δημήτριας: διδακτορική διατριβή 

      Χαπέσιη, Ευρούλα Α. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2007-06)
      Στόχος της παρούσας διδακτορικής διατριβής ήταν η σύνθεση υλικών βασισμένων στη δημήτρια και η μελέτη των ιδιοτήτων τους όπως είναι η δομή και η υφή τους. Η παρούσα ερευνητική εργασία εστιάζεται στη σύνθεση και μελέτη των ...

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