A [Mn32] double-decker wheel
Date
2011Author
Manoli, MariaInglis, R.
Manos, Manolis J.
Nastopoulos, Vassilios
Wernsdorfer, W.
Brechin, E. K.
Tasiopoulos, Anastasios J.
ISSN
1433-7851Source
Angewandte Chemie - International EditionVolume
50Issue
19Pages
4441-4444Google Scholar check
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Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example of its type, and it displays SMM behavior with the largest effective barrier to magnetization relaxation (Ueff≈ 44.5 K) for any molecular wheel. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.