Browsing by Subject "Nuclearity"

Now showing items 1-4 of 4

    • Article  

      Diol-type ligands as central 'players' in the chemistry of high-spin molecules and single-molecule magnets 

      Tasiopoulos, Anastasios J.; Perlepes, Spyros P. (2008)
      The combination of diol-type ligands with paramagnetic transition metal ions has led to the isolation of a host of new homometallic and heterometallic clusters, high-spin molecules and single molecule magnets ranging in ...
    • Article  

      High nuclearity structurally-related Mn supertetrahedral T4 aggregates 

      Skordi, Katerina; Anastassiades, Antonis; Fournet, Adeline D.; Fournet, Adeline D.; Schulze, Michael; Wernsdorfer, Wolfgang; Christou, George; Nastopoulos, Vassilios; Perlepes, Spyros P.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J. (Royal Society of Chemistry, 2021-12-04)
      The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal ...
    • Article  

      Magnetic "Molecular Oligomers" Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragment 

      Manoli, Maria; Alexandrou, Sofia; Pham, L.; Lorusso, G.; Wernsdorfer, W.; Evangelisti, M.; Christou, George; Tasiopoulos, Anastasios J. (2016)
      Two nanosized Mn49 and Mn25Na4 clusters based on analogues of the high-spin (S=22) [MnIII 6MnII 4(μ4-O)4]18+ supertetrahedral core are reported. Mn49 and Mn25Na4 complexes consist of eight and four decametallic supertetrahedral ...
    • Article  

      A [Mn32] double-decker wheel 

      Manoli, Maria; Inglis, R.; Manos, Manolis J.; Nastopoulos, Vassilios; Wernsdorfer, W.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2011)
      Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example ...