Browsing by Subject "oxidation reduction reaction"
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Aerial Oxidation of a VIV-Iminopyridine Hydroquinonate Complex: A Trap for the VIV-Semiquinonate Radical Intermediate (2015)The reaction of 2,5-bis[N,N′-bis(2-pyridyl-aminomethyl)aminomethyl]-p-hydroquinone (H2bpymah) with VO2+ salts in acetonitrile or water at a low pH (2.2-3.5) results in the isolation of [VIV(O)(Cl)2(μ-bpymah)], the ...
Synthesis, characterization, and study of octanuclear iron-oxo clusters containing a redox-active Fe4O4-cubane core (2008)A one-pot synthetic procedure yields the octanuclear FeIII complexes Fe8(μ4-O)4(μ-pz*) 12X4, where X = Cl and pz* = pyrazolate anion (pz = C3H3N2-) (1), 4-Cl-pz (2), and 4-Me-pz (3) or X = Br and pz* = pz (4). The crystal ...