Browsing by Subject "vanadic acid"
Now showing items 1-5 of 5
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Donor atom electrochemical contribution to redox potentials of square pyramidal vanadyl complexes
(2015)A simple donor atom additivity relationship has been used to calculate the donor atom electrochemical contribution (DEC) of the Oac (acetylacetonate-enolic oxygen), OPh (phenolic oxygen), SPh (mercaptophenol sulfur), Nam ...
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Is vanadate reduced by thiols under biological conditions? Changing the Redox potential of V(V)/V(IV) by complexation in aqueous solution
(2010)Although dogma states that vanadate is readily reduced by glutathione, cysteine, and other thiols, there are several examples documenting that vanadium(V)-sulfur complexes can form and be observed. This conundrum has ...
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Oxidovanadium(IV/V) complexes as new redox mediators in dye-sensitized solar cells: A combined experimental and theoretical study
(2015)Corrosiveness is one of the main drawbacks of using the iodide/triiodide redox couple in dye-sensitized solar cells (DSSCs). Alternative redox couples including transition metal complexes have been investigated where ...
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Vanadium chemistry and biochemistry of relevance for use of vanadium compounds as antidiabetic agents
(1995)The stability of 11 vanadium compounds is tested under physiological conditions and in administration fluids. Several compounds including those currently used as insulin-mimetic agents in animal and human studies are stable ...
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Vanadium(V) compounds with the bis-(hydroxylamino)-1,3,5-triazine ligand, H2bihyat: Synthetic, structural, and physical studies of [V 2VO3(bihyat)2] and of the enhanced hydrolytic stability species cis-[VVO2(bihyat)] -
(2008)Reaction of the ligand 2,6-bis[hydroxy(methyl)amino]-4-morpholino-1,3,5- triazine (H2bihyat) with NaVVO3 in aqueous solution followed by addition of either Ph4PCl or C(NH 2)3Cl, respectively, gave the mononuclear vanadium(V) ...