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A hexameric [Mn III 18 Na6] wheel based on [Mn III 3 O]7+ sub-units
(2016)
A novel hexameric [MnIII18Na6] wheel-like aggregate consisting of [MnIII3O] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular ...
A 1-D coordination polymer based on a Mn40 octagonal super-structure
(2013)
A 1-D coordination polymer, constructed using a combination of diols and phenolic oximes, contains a novel [Mn9] sub-unit, a nanosized [Mn40] octagonal super-structure and a [Mn21] repeating unit. © 2013 The Royal Society ...
Insertion of functional groups into a Nd 3+ metal-organic framework via single-crystal-to-single-crystal coordinating solvent exchange
(2012)
Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or ...
A highly porous interpenetrated metal-organic framework from the use of a novel nanosized organic linker
(2011)
The initial use of a novel elongated tricarboxylic acid H3hmpib in metal-organic framework (MOF) chemistry resulted in a [Zn4O(hmpib) 2] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal ...
Synthesis and characterization of a linear [Mn3(O 2CMe)4(py)8]2+ complex
(2010)
Two new compounds that consist of the linear trinuclear manganese(II) cation [Mn3(O2CMe)4(py)8] 2+ cocrystallizing with different counteranions (I3 -, [1]
A missing oxidation-state level in the family of polyoxo(azide)octadecavanadate(IV/V) clusters: Synthesis, structure and antitumoural properties of [VIV11VV7O44(N3)]10 - In a sodium containing-3D architecture
(2016)
The missing VIV11VV7 oxidation-state member of the polyoxooctadecavanadate(IV/V) - azide family of inorganic host-guest systems has been incorporated in a NaI-containing 3D architecture
Synthesis, experimental and theoretical investigation of a new type nickel dithiolene complex
(2013)
A new nickel complex with an extended multisulfur dithiolene ligand, [Ni(dmeodddt)2] (dmeodddt = 5,6-dimethoxy-5,6-dihydro-1,4-dithiine-2, 3-dithiolate), has been synthesized and characterized by IR, Raman, UV-Vis and NMR ...
Unexpected formation, X-ray structure, and characterization of the triangular [Ti3O(OMe)6(σ5-C 5H5)3](I3) complex from hydrolysis and methanolysis of [Ti(σ5-C5H5) 2I2]
(2011)
A convenient route has been developed for the formation of [Ti IV3O(OMe)6(σ5-C 5H5)3](I3) (2) involving methanolysis (and possibly hydrolysis) of species derived from titanocene diiodide, [TiIV(σ5-C5H5) 2I2] (1), under ...