A hexameric [Mn III 18 Na6] wheel based on [Mn III 3 O]7+ sub-units
Brechin, E. K.
Tasiopoulos, Anastasios J.
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A novel hexameric [MnIII18Na6] wheel-like aggregate consisting of [MnIII3O] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [MnIII3O] triangles, and the only one with a wheel-like metal topology. © The Royal Society of Chemistry 2016.