Browsing by Subject "magnetism"

Article

Correlations of synthetic, spectroscopic, structural, and speciation studies in the biologically relevant Cobalt(II) - Citrate system: The tale of the first aqueous dinuclear Cobalt(II) - Citrate complex

Kotsakis, N.; Raptopoulou, C. P.; Tangoulis, V.; Terzis, A.; Giapintzakis, John; Jakusch, T.; Kiss, T.; Salifoglou, A. (2003)

Synthetic efforts targeting soluble species of Co(II) with the low molecular mass physiological ligand citric acid led to the isolation of the first dinuclear complex [Co2(C6H5O7)2 (H2O)4]2-, at pH ∼5, in the form of its ...

Article

Fabrication, characterization, and evaluation in drug release properties of magnetoactive poly(ethylene oxide)-poly(l -lactide) electrospun membranes

Savva, I.; Odysseos, A. D.; Evaggelou, L.; Marinica, O.; Vasile, E.; Vekas, L.; Sarigiannis, Y.; Krasia-Christoforou, T. (2013)

The fabrication of electrospun magnetoactive fibrous nanocomposite membranes based on the water-soluble and biocompatible poly(ethylene oxide) (PEO), the biocompatible and biodegradable poly(l-lactide) (PLLA) and preformed ...

Article

Ferromagnetic and antiferromagnetic interactions in lanthanum cobalt oxide at low temperatures

Androulakis, J.; Katsarakis, N.; Giapintzakis, John (2001)

Systematic dc and ac magnetic susceptibility studies have been performed on single-phase (formula presented) powder samples. Evidence is presented in support of the existence of ferromagnetic (FM1, FM2) and antiferromagnetic ...

Article

Impurity-induced antiferromagnetic order in the Haldane-gap compound PbNi2-xMgxV2O8 (x=0.24)

Lappas, A.; Alexandrakis, V.; Giapintzakis, John; Pomjakushin, V.; Prassides, K.; Schenck, A. (2002)

An investigation of the effect of nonmagnetic Mg doping in the Haldane gap system PbNi2V2O8 is presented. Specifically, the magnetic properties of the quasi-one-dimensional compound PbNi2-xMgxV2O8 (x =0.24), located in the ...

Article

LaSrMnCoO6: A new cubic double perovskite oxide

Androulakis, J.; Katsarakis, N.; Giapintzakis, John; Vouroutzis, N.; Pavlidou, E.; Chrissafis, K.; Polychroniadis, E. K.; Perdikatsis, V. (2003)

Single-phase polycrystalline powder samples of the double perovskite oxide LaSrMnCoO6 were synthesized by the Pechini (citrate-gel) technique. The structural, magnetic and electrical properties of the obtained powders were ...

Article

Manganese citrate chemistry: Syntheses, spectroscopic studies, and structural characterizations of novel mononuclear, water-soluble manganese citrate complexes

Matzapetakis, M.; Karligiano, N.; Bino, A.; Dakanali, M.; Raptopoulou, C. P.; Tangoulis, V.; Terzis, A.; Giapintzakis, John; Salifoglou, A. (2000)

The first two mononuclear manganese citrate complexes, (NH4)4[Mn(II)(C6H5O7)2] (1) and (NH4)5[Mn(III)(C6H4O7)2]·2H2O (2) were synthesized in aqueous solutions near physiological pH values. They were isolated in their pure ...

Article

Multiresponsive polymer conetworks capable of responding to changes in pH, temperature, and magnetic field: Synthesis, characterization, and evaluation of their ability for controlled uptake and release of solutes

Papaphilippou, P.; Christodoulou, M.; Marinica, O. M.; Taculescu, A.; Vekas, L.; Chrissafis, K.; Krasia-Christoforou, T. (2012)

This study deals with the preparation of novel multiresponsive (magnetoresponsive, thermoresponsive and pH-responsive) nanocomposite conetworks consisting of oleic acid-coated magnetite nanoparticles (OA•Fe 3O 4), ...

Article

Relations of crystal structure to magnetic properties in the quasi-one-dimensional compound PbNi1.88Mg0.12V 2O8

Mastoraki, I.; Lappas, A.; Giapintzakis, John; Többens, D.; Hernández-Velasco, J. (2004)

The crystal structure of the quasi-one-dimensional oxide PbNi 1.88Mg0.12V2O8 has been studied by Rietveld analysis of combined high-resolution neutron and X-ray powder diffraction data at 300K and at low temperatures. The ...

Article

Superparamagnetic hybrid micelles, based on iron oxide nanoparticles and well-defined diblock copolymers possessing β-ketoester functionalities

Papaphilippou, P.; Loizou, L.; Popa, N. C.; Han, A.; Vekas, L.; Odysseos, A.; Krasia-Christoforou, T. (2009)

The quality of surface coating of magnetic nanoparticles destined as nanoprobes in clinical applications is of utmost significance for their colloidal stability and biocompatibility. A novel approach for the fabrication ...

Article

Synthesis and structural and spectroscopic characterization of a complex between Co(II) and imino-bis(methylphosphonic acid): Gaining insight into biologically relevant metal-ion phosphonate interactions or looking at a new Co(II)-organophosphonate material?

Jankovics, H.; Daskalakis, M.; Raptopoulou, C. P.; Terzis, A.; Tangoulis, V.; Giapintzakis, John; Kiss, T.; Salifoglou, A. (2002)

Cobalt is an essential metal ion involved in key biomolecules, regulating processes in human physiology. As a metal ion, Co(II) assumes forms, which are dictated by the nature of organic binders in biological fluids, and ...

Article

Synthesis, structure, magnetic properties and aqueous solution characterization of p-hydroquinone and phenol iminodiacetate copper(ii) complexes

Stylianou, M.; Drouza, C.; Viskadourakis, Z.; Giapintzakis, John; Keramidas, A. D. (2008)

The reaction of Cu2+ acetate monohydrate with 2-[N,N′-bis(carboxymethyl)aminomethyl]-4-carboxyphenol (H 4cacp), 2-[N,N-bis(carboxymethyl)aminomethyl]hydroquinone (H 4cah) and the dinucleating 2,5-bis[N,N-bis(carboxymethy ...

Article

Thickness dependence of Hall transport in Ni1.15Mn 0.85Sb thin films on silicon

Branford, W. R.; Clowes, S. K.; Bugoslavsky, Y. V.; Gardelis, S.; Androulakis, J.; Giapintzakis, John; Grigorescu, C. E. A.; Manea, S. A.; Freitas, R. S.; Roy, S. B.; Cohen, L. F. (2004)

Highly spin polarized Heusler alloys, NiMnSb and Co2MnSi, attract a great deal of interest as potential spin injectors for spintronic applications. Spintronic devices require control of interfacial properties at the ...

Article

Unconventional magnetism in all-carbon nanofoam

Rode, A. V.; Gamaly, E. G.; Christy, A. G.; Gerald, J. G. Fitz; Hyde, S. T.; Elliman, R. G.; Luther-Davies, B.; Veinger, A. I.; Androulakis, J.; Giapintzakis, John (2004)

We report production of nanostructured magnetic carbon foam by a high-repetition-rate, high-power laser ablation of glassy carbon in Ar atmosphere. A combination of characterization techniques revealed that the system ...

Article

Vanadium(IV) - Citrate complex interconversions in aqueous solutions. A pH-dependent synthetic, structural, spectroscopic, and magnetic study

Tsaramyrsi, M.; Kaliva, M.; Salifoglou, A.; Raptopoulou, C. P.; Terzis, A.; Tangoulis, V.; Giapintzakis, John (2001)

Citrate is abundantly encountered in biological fluids as a natural metal ion chelator. Vanadium participates in biological processes as a catalyst in the active sites of metalloenzymes, as a metabolic regulator, as a ...