Mixed Transition-Metal - Lanthanide Complexes at Higher Oxidation States: Heteronuclear CeIV-MnIV Clusters
Date
2004
ISSN
1433-7851Source
Angewandte Chemie - International EditionVolume
43Issue
3Pages
345-349Google Scholar check
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Wheels within wheels: A new family of mixed cerium(IV)-manganese(IV) clusters has been prepared spanning a range of Ce:Mn ratios from 3:2 to 1:6. The unusual core of the latter CeMn6 complex is shown (Ce green, Mn blue, O red). All the compounds exhibit antiferromagnetic interactions between their constituent MnIV ions.