Mixed Transition-Metal - Lanthanide Complexes at Higher Oxidation States: Heteronuclear CeIV-MnIV Clusters
AuthorTasiopoulos, Anastasios J.
O'Brien, T. A.
Abboud, K. A.
SourceAngewandte Chemie - International Edition
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Wheels within wheels: A new family of mixed cerium(IV)-manganese(IV) clusters has been prepared spanning a range of Ce:Mn ratios from 3:2 to 1:6. The unusual core of the latter CeMn6 complex is shown (Ce green, Mn blue, O red). All the compounds exhibit antiferromagnetic interactions between their constituent MnIV ions.