Browsing Τμήμα Χημείας / Department of Chemistry by Author "Chilas, G. I."
Now showing items 1-3 of 3
-
Article
Molybdenum(VI) coordination chemistry of the N,N-disubstituted bis(hydroxylamido)-1,3,5-triazine ligand, H2bihyat. Water-assisted activation of the MoVI=O bond and reversible dimerization of cis-[MoVIO2(bihyat)] to [MoVI2O 4(bihyat)2(H2O)2]
Stylianou, Marios; Nikolakis, Vladimiros A.; Chilas, G. I.; Jakusch, T.; Vaimakis, T.; Kiss, Tamás; Sigalas, Michael P.; Keramidas, Anastasios D.; Kabanos, Themistoklis A. (2012)Reaction of the N,N-disubstituted bis(hydroxylamino) ligand 2,6-bis[hydroxy(methyl)amino]-4-morpholino-1,3,5-triazine (H2bihyat) with cis-[MoVIO2(acac)2] in tetrahydrofuran resulted in isolation of the mononuclear compound ...
-
Article
Oxovanadium(IV)-sulfite compounds: Synthesis and structural and physical studies
Chilas, G. I.; Miras, Haralampos N.; Manos, Manolis J.; Woollins, J. D.; Slawin, A. M. Z.; Stylianou, Marios; Keramidas, Anastasios D.; Kabanos, Themistoklis A. (2005)Reaction of VIVOCl2 in strongly acidic aqueous solution with either (NH4)2SO3 or Na 2SO3 and Bu4NBr at ∼70 °C in the pH range 2.5-4.5 gives the clusters (NH4)2{[V 4IV)(μ4-O)2(μ3-OH) 2](VIVO)2(μ3-SO3) 4O4(H2O)2} and (n-Bu ...
-
Article
Polynuclear cobalt(II/III) sulfites: Synthesis, structure, and magnetic properties of the octanuclear cluster (NH4)11(Li⊂ [Co4IICo4III(SO3) 16(NH3)8])·10H2O encapsulating a lithium cation
Chilas, G. I.; Stylianou, Marios; Kubicki, Maciej; Vaimakis, T.; Kögerler, P.; Keramidas, Anastasios D.; Kabanos, Themistoklis A. (2008)Partial oxidation of an aqueous solution of CoIICl 2·6H2O with (NH4)6[Mo 7VIO24]·4H2O in the presence of (NH4)2SO3·H2O and LiCl, at pH ≈ 5.3, leads to isolation of the octanuclear cluster (NH 4)11(Li⊂[Co4IICo 4III(SO3)16(NH3) ...