Browsing Τμήμα Χημείας / Department of Chemistry by Author "Gaidamauskas, E."
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Is vanadate reduced by thiols under biological conditions? Changing the Redox potential of V(V)/V(IV) by complexation in aqueous solution
Crans, D. C.; Zhang, B.; Gaidamauskas, E.; Keramidas, Anastasios D.; Willsky, G. R.; Roberts, C. R. (2010)Although dogma states that vanadate is readily reduced by glutathione, cysteine, and other thiols, there are several examples documenting that vanadium(V)-sulfur complexes can form and be observed. This conundrum has ...