Browsing Τμήμα Χημείας / Department of Chemistry by Author "Skordi, Katerina"
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Article
2-hydroxybenzophenone-controlled self-assembly of enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”-like topology
Mylonas-Margaritis, Ioannis; Kitos, Alexandros A.; Panteli, Chrysanthi C.; Skordi, Katerina; Tasiopoulos, Anastasios J.; Bekiari, Vlasoula; Escuer, Albert; Perlepes, Spyros P. (2017)Enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”- or “sandglass”-like topology have been synthesized via 2-hydroxybenzophenone-controlled hydrolysis of the metal ions in ethanol
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Article
Heterometallic MnIII4Ln2 (Ln = Dy, Gd, Tb) Cross-Shaped Clusters and Their Homometallic MnIII4MnII2 Analogues
Savva, Maria; Skordi, Katerina; Fournet, A. D.; Thuijs, A. E.; Christou, George; Perlepes, Spyros P.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J. (2017)The employment of di-2-pyridyl ketone, (py)2CO, in heterometallic Mn/4f and homometallic Mn cluster chemistry has yielded six MnIII4Ln2 and two MnIII4MnII2 structurally related clusters, namely, [Mn4Ln2O2{(py)2CO2}4(NO3) ...
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Article
Homometallic {Mn10} and heterometallic {Mn6Ca4} supertetrahedra exhibiting an unprecedented {MnIII9MnII} oxidation state level and heterometal ions distribution
Skordi, Katerina; Papatriantafyllopoulou, Constantina; Zartilas, Sotiris; Poole, Katye M.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2018)Two novel decametallic clusters displaying a supertetrahedral structural core are discussed, a homometallic compound [MnIII9MnII(μ4-O)4(μ3-OMe)3(btH)3(ed)3(PhCO2)6]·6Η2Ο (1·6Η2Ο) (btH3 = (±)-1,2,4-butanetriol