Browsing Τμήμα Χημείας / Department of Chemistry by Author "Vougioukalakis, G. C."
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Article
Addition of Electron-Rich Aromatics to Azafullerenium Carbocation. A Stepwise Electrophilic Substitution Mechanism
Vougioukalakis, G. C.; Chronakis, Nikos; Orfanopoulos, Michael (2003)(Matrix presented) The reaction between the C59N+ carbocation and the electron-rich aromatic compounds toluene and anisole has been mechanistically studied. The measured intermolecular kinetic isotope effects are consistent ...
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Article
Synthesis and self-photooxygenation of alkenyl-linked [60]fullerene derivatives. A regioselective ene reaction
Chronakis, Nikos; Vougioukalakis, G. C.; Orfanopoulos, Michael (2002)(equation presented) Alkenyl-linked C60 derivatives undergo self-photooxygenation regioselectively, by the preferential abstraction of allylic hydrogens on the fullerene side of the double bond.