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Solvent-dependent access to mono- and dinuclear copper(II) assemblies based on a flexible imidazole ligand
(2016)
Seven copper(ii) complexes with the less bulky (compared to bis-phenyl-substituted imidazoles used in our previous studies) monodentate 2-phenylimidazole (LH) ligand have been prepared from the general CuII/X-/LH (X- = ...
Pentanuclear complexes with unusual structural topologies from the initial use of two aliphatic amino-alcohol ligands in Fe chemistry
(2012)
Five novel pentanuclear Fe 3+ clusters with the aliphatic amino-alcohol ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [Fe 5(μ 3-Ο) 2(L) 4(O 2CR) 7] [L = ap -, R = Ph (1)
Binding of ligands containing carbonyl and phenol groups to iron(iii): new Fe6, Fe10 and Fe12 coordination clusters
(2017)
The initial use of ligands 2′-hydroxyacetophenone (HL1), 2-hydroxybenzophenone (HL2) and 2,2′-dihydroxybenzophenone (H2L3) in iron(iii) chemistry is described. The syntheses and crystal structures are reported for five ...
Synthesis, magnetic and spectroscopic characterization of a new Fe 7 cluster with a six-pointed star topology
(2013)
A heptanuclear FeIII7 cluster is reported, prepared from the reaction of [Fe3O(O2CPh)6(H 2O)3]+ and a combination of aliphatic aminoalcohol ligands, namely apH (3-amino-1-propanol) and hmpipH (2-hydroxymethyl piperidine). ...
Heterometallic FeIII-CeIV complexes from the use of aliphatic aminoalcohol ligands
(2013)
Six novel heteronuclear FeIII/CeIV clusters with the ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [FeIII4CeIV6O8(L) 4((CH3)3CCO2)12(RCO 2)4] (R = CH3, L = ap-, 1
Interactions of hydroxycarbamide (Hydroxyurea) with Iron and copper: Implications on toxicity and therapeutic strategies
(2011)
Presented at the 19th International Conference on Chelation, London, UK, 13-16 November 2009Preliminary spectrophotometric and potentiometric studies have shown that hydroxycarbamide or hydroxyurea (HU) can interact with ...
Metal ion-assisted transformations of 2-pyridinealdoxime and hexafluorophosphate
(2012)
Metal-ion mediated reactions of 2-pyridinealdoxime and hexafluorophosphate lead to Zn II complexes containing picolinic acid, picolinamide and monofluorophosphate (-2) as ligands. © 2012 The Royal Society of Chemistry.
Novel mixed metal Ag(I)-Sb(III)-metallotherapeutics of the NSAIDs, aspirin and salicylic acid: Enhancement of their solubility and bioactivity by using the surfactant CTAB
(2015)
The already known Ag(I)-Sb(III) compound of the formula {Ag(Ph3Sb)3(NO3)} (1) and two novel mixed metal Ag(I)-Sb(III) metallotherapeutics of the formulae {Ag(Ph3Sb)3(SalH)}(2) and {Ag(Ph3Sb)3(Asp)}(3) (SalH2 = salicylic ...
Triangular NiII2LnIII and Ni II2YIII complexes derived from di-2-pyridyl ketone: Synthesis, structures and magnetic properties
(2011)
The synthetic investigation of the NiII/M(NO3) 3·6H2O/di-2-pyridyl ketone [(py)2CO] tertiary reaction system in EtOH has yielded triangular Ni2M cationic complexes (M = lanthanide, Y). The reaction between Ln(NO3) 3·6H2O, ...
Matrix assisted pulsed laser evaporation of Mn 12(Propionate) thin films
(2012)
Single molecule magnets are of great interest due to a multitude of potential applications for some of which thin films are required. Traditional physical vapor deposition techniques are not suitable for the deposition of ...