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The effect of Ti4+ dopant in the 5 wt% Ni/Ce1-xTixO2-δ catalyst on the carbon pathways of dry reforming of methane studied by various transient and isotopic techniques
(2019)
The carbon pathways in the dry reforming of methane with carbon dioxide (DRM) towards syngas at 750 °C have been investigated for the first time over 5 wt% Ni supported on Ti4+-doped ceria using various transient and ...
The effect of Pt on the carbon pathways in the dry reforming of methane over Ni-Pt/Ce0.8Pr0.2O2-δ catalyst
(2019)
The present work extensively discusses the carbon pathways in the dry reforming of methane with carbon dioxide (DRM) at 750 °C towards syngas (CO/H2 ˜ 1) over 5 wt% Ni, 0.5 wt% Pt and their bimetallic alloy (5 wt% Ni-0.5 wt% ...
Regioselective Fluorination of 7-Oxo-1,2,4-benzotriazines Using Selectfluor
(2019)
7-Oxo-1,2,4-benzotriazines (benzo[1,2,4]triazin-7-ones) are reversible thioredoxin reductase inhibitors that exhibit very strong correlations to pleurotin. In this article, we provide the first synthesis of fluorinated ...
3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one
(2019)
Stille coupling of 5-chloro-4-oxo-4H-1,2,6-thiadiazin-3-yl trifluoromethanesulfonate (7) with tributyl(3-n-hexylthien-2-yl)stannane and Pd(Ph3P)2Cl2 in PhMe at ca. 20 °C, for 24 h gave 3-chloro-5-(3-n-hexylthien-2-yl)-4H ...
LC-ESI-MS/MS determination of oxyhalides (chlorate, perchlorate and bromate) in food and water samples, and chlorate on household water treatment devices along with perchlorate in plants
(2019)
The results of the validation study of the LC-ESI-MS/MS method for the determination of chlorate (ClO3-), perchlorate (ClO4-) and bromate (BrO3-) in water and food samples are summarized. Towards this, 284 samples of ...
Synergistic enantioseparation systems with either cyclodextrins or cyclofructans and L-alanine Tert butyl ester lactate
(2019)
The combined use of chiral ionic liquids (CILs) and conventional chiral selectors (CSs) in CE, to establish a synergistic system, has proven to be an effective approach for the separation of enantiomeric pairs. In this ...
Antiproliferative activity and apoptosis induction, of organo-antimony(III)–copper(I) conjugates, against human breast cancer cells
(2019)
Three known organo-antimony(III)–copper(I), mixed-metal small bioactive molecules (SBAMs) of formula [Cu(tpSb)3Cl] (1), [Cu2(tpSb)4Br2] (2) and [Cu2(tpSb)4I2] (3) (tpSb = triphenylstibine) were used for the clarification ...