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A highly porous interpenetrated metal-organic framework from the use of a novel nanosized organic linker
(2011)
The initial use of a novel elongated tricarboxylic acid H3hmpib in metal-organic framework (MOF) chemistry resulted in a [Zn4O(hmpib) 2] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal ...
Synthesis, experimental and theoretical investigation of a new type nickel dithiolene complex
(2013)
A new nickel complex with an extended multisulfur dithiolene ligand, [Ni(dmeodddt)2] (dmeodddt = 5,6-dimethoxy-5,6-dihydro-1,4-dithiine-2, 3-dithiolate), has been synthesized and characterized by IR, Raman, UV-Vis and NMR ...
Unexpected formation, X-ray structure, and characterization of the triangular [Ti3O(OMe)6(σ5-C 5H5)3](I3) complex from hydrolysis and methanolysis of [Ti(σ5-C5H5) 2I2]
(2011)
A convenient route has been developed for the formation of [Ti IV3O(OMe)6(σ5-C 5H5)3](I3) (2) involving methanolysis (and possibly hydrolysis) of species derived from titanocene diiodide, [TiIV(σ5-C5H5) 2I2] (1), under ...
One-step conversion of 2-Amino- N ′-arylbenzamidines into 3-aryl-4-imino-3,4-dihydroquinazoline-2-carbonitriles using 4,5-dichloro-1,2,3- dithiazolium chloride
(2013)
2-Amino-N′-arylbenzamidines react with 4,5-dichloro-1,2,3- dithiazolium chloride (Appel salt) in the presence of Hünig's base (2 equiv) to give in one step 3-aryl-4-imino-3,4-dihydroquinazoline-2-carbonitriles in 53-81% ...
Structural characterization of the {3[BPMTU]+• 3[X] -• nH2O} salts (BPMTU = 1,3-bis(3-pyridylmethyl)-2- thiourea and X = Cl, Br, I). A polychlorine network based on O⋯Cl - and OH⋯Cl- interactions
(2011)
Ionic salts with the formulae {3[BPMTU]+ 3[X]- nH2O} (BPMTU = 1,3-bis(3-pyridylmethyl)-2-thiourea, X = Cl - and n = 1.5 (1), X = Br-and n = 1 (2), X = I- and n = 1 (3)) were synthesized. The compounds have been characterized ...
Synthesis, structural characterization and in vitro inhibitory studies against human breast cancer of the bis-(2,6-di-tert-butylphenol)tin(iv) dichloride and its complexes
(2012)
Four new organotin(iv) complexes of bis-(2,6-di-tert-butylphenol)tin(iv) dichloride [(tert-Bu-)2(HO-Ph)]2SnCl2 (1) with the heterocyclic thioamides 2-mercapto-pyrimidine (PMTH), 2-mercapto-4-methyl- pyrimidine (MPMTH), ...
Synthesis and non-linear optical properties of some novel nickel derivatives
(2010)
The synthesis of a new nickel complex with an extended multi-sulfur dithiolene ligand Ni(etodddt)2 (etodddt = 4,5-(1,4-oxathiane-2,3- diyldithio)-1,3-dithiole) is described. It is characterized analytically and spectroscopically. ...
A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake
(2015)
The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...
Synthesis, characterization and biological studies of new antimony(III) halide complexes with ω-thiocaprolactam
(2012)
Three new antimony(III) halide complexes (SbX 3, X = Cl, Br and I) with the heterocyclic thione ω-thiocaprolactam (1-azacycloheptane-2- thione, (Hthcl)) of formulae {[SbCl 2(μ 2-Cl)(Hthcl) 2] n} (1), {[(SbBr 2(μ 2-Br)(Hthcl) ...