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Now showing items 41-50 of 50
Tricyclo[3.3.1.03,7]nonane-3,7-diyl bis(methanesulfonate)
(2010)
The crystal structure of the title compound, C11H 18O6S2, was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the ...
Interesting copper(ii)-assisted transformations of 2-acetylpyridine and 2-benzoylpyridine
(2016)
The reactions of various copper(ii) sources with 2-acetylpyridine, (py)(me)CO, and 2-benzoylpyridine, (py)(ph)CO, under strongly basic conditions have been studied and novel ligand transformations have been discovered. ...
The search for cobalt single-molecule magnets: A disk-like Co IIICoII 6 cluster with a ligand derived from a novel transformation of 2-acetylpyridine
(2011)
The initial employment of 2-acetylpyridine, (py)(Me)CO, in Co cluster chemistry is reported, and the synthesis, crystal structure, and full magnetic study of [Co7(OH)6(L)6](ClO4) 3·1.6H2O (1·1.6H2O) are described
Solvent-dependent access to mono- and dinuclear copper(II) assemblies based on a flexible imidazole ligand
(2016)
Seven copper(ii) complexes with the less bulky (compared to bis-phenyl-substituted imidazoles used in our previous studies) monodentate 2-phenylimidazole (LH) ligand have been prepared from the general CuII/X-/LH (X- = ...
Pentanuclear complexes with unusual structural topologies from the initial use of two aliphatic amino-alcohol ligands in Fe chemistry
(2012)
Five novel pentanuclear Fe 3+ clusters with the aliphatic amino-alcohol ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [Fe 5(μ 3-Ο) 2(L) 4(O 2CR) 7] [L = ap -, R = Ph (1)
Heterometallic FeIII-CeIV complexes from the use of aliphatic aminoalcohol ligands
(2013)
Six novel heteronuclear FeIII/CeIV clusters with the ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [FeIII4CeIV6O8(L) 4((CH3)3CCO2)12(RCO 2)4] (R = CH3, L = ap-, 1
Triangular NiII2LnIII and Ni II2YIII complexes derived from di-2-pyridyl ketone: Synthesis, structures and magnetic properties
(2011)
The synthetic investigation of the NiII/M(NO3) 3·6H2O/di-2-pyridyl ketone [(py)2CO] tertiary reaction system in EtOH has yielded triangular Ni2M cationic complexes (M = lanthanide, Y). The reaction between Ln(NO3) 3·6H2O, ...
Water-stable 2-D Zr MOFs with exceptional UO22+ sorption capability
(Royal Society of Chemistry, 2019-12-02)
Two new 8-connected 2-D MOFs, UCY-13 and UCY-14, based on Zr6 secondary building units (SBUs) and angular dicarboxylate ligands are reported. UCY-13 and UCY-14 display remarkable stability in various types of aqueous media, ...