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Micellization behavior of poly(η-butyl methacrylate)-block-poly(2- (acetoacetoxy)ethyl methacrylate)

dc.contributor.authorSigel, R.en
dc.contributor.authorKrasia-Christoforou, T.en
dc.contributor.authorBelow, I.en
dc.contributor.authorSchlaad, H.en
dc.creatorSigel, R.en
dc.creatorKrasia-Christoforou, T.en
dc.creatorBelow, I.en
dc.creatorSchlaad, H.en
dc.date.accessioned2019-05-06T12:24:35Z
dc.date.available2019-05-06T12:24:35Z
dc.date.issued2009
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/48825
dc.description.abstractA series of poly(η-butyl methacrylate)-block-poly(2-(acetoacetoxy)ethyl methacrylate)s (PBMA-b-PAEMA) were studied according to the formation of core-shell micelles in dilute cyclohexane solution (PBMA-shell, PAEMA-core). Although being a strongly segregating system, the appearance of different shapes of micelles could not appropriately be described by simple space-filling arguments within the geometric model of Antonietti and Förster et al. [J. Chem. Phys. 1996, 104, 9956-9970]. The model was refined through introduction of the aspect ratio of the core-forming monomer unit for the calculation of geometric packing parameters. © 2009 American Chemical Society.en
dc.language.isoengen
dc.sourceMacromoleculesen
dc.subjectIsomersen
dc.subjectMicellesen
dc.subjectEthyl methacrylatesen
dc.subjectAspect ratioen
dc.subjectButyl methacrylatesen
dc.subjectCore-shellen
dc.subjectCyclohexane solutionsen
dc.subjectGeometric modelsen
dc.subjectMicellizationen
dc.subjectMicellization behavioren
dc.subjectMonomer unitsen
dc.subjectPacking parametersen
dc.subjectSpace-fillingen
dc.titleMicellization behavior of poly(η-butyl methacrylate)-block-poly(2- (acetoacetoxy)ethyl methacrylate)en
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ma9003727
dc.description.volume42
dc.description.startingpage4257
dc.description.endingpage4261
dc.author.facultyΠολυτεχνική Σχολή / Faculty of Engineering
dc.author.departmentΤμήμα Μηχανικών Μηχανολογίας και Κατασκευαστικής / Department of Mechanical and Manufacturing Engineering
dc.type.uhtypeArticleen
dc.contributor.orcidKrasia-Christoforou, T. [0000-0002-9915-491X]
dc.description.totalnumpages4257-4261
dc.gnosis.orcid0000-0002-9915-491X


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