dc.contributor.author | Alexandropoulos, Dimitris I. | en |
dc.contributor.author | Papatriantafyllopoulou, Constantina | en |
dc.contributor.author | Li, C. -L | en |
dc.contributor.author | Cunha-Silva, L. | en |
dc.contributor.author | Manos, Manolis J. | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Wernsdorfer, W. | en |
dc.contributor.author | Christou, George | en |
dc.contributor.author | Stamatatos, Theocharis C. | en |
dc.creator | Alexandropoulos, Dimitris I. | en |
dc.creator | Papatriantafyllopoulou, Constantina | en |
dc.creator | Li, C. -L | en |
dc.creator | Cunha-Silva, L. | en |
dc.creator | Manos, Manolis J. | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Wernsdorfer, W. | en |
dc.creator | Christou, George | en |
dc.creator | Stamatatos, Theocharis C. | en |
dc.date.accessioned | 2019-11-21T06:16:19Z | |
dc.date.available | 2019-11-21T06:16:19Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1434-1948 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55247 | |
dc.description.abstract | The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded structurally interesting MnII/III14 and Mn II/III/IV16 clusters, respectively. In both complexes, the end-on bridging cyanato groups show an obvious preference in binding through their O atom, a significantly different ligation than that for the homoatomic-type N3- ligand. The Mn14 compound shows entirely visible out-of-phase signals below 5 K and large hysteresis loops below 2 K. The use of cyanato groups in higher oxidation state Mn cluster chemistry, in combination with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded structurally new Mn14 and Mn16 clusters, respectively | en |
dc.description.abstract | the Mn14 compound shows entirely visible out-of-phase signals below 5 K and large hysteresis loops below 2 K. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | en |
dc.source | European Journal of Inorganic Chemistry | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84876535394&doi=10.1002%2fejic.201300099&partnerID=40&md5=98139d2d887f65d8991d87983751c608 | |
dc.subject | Manganese | en |
dc.subject | Cyanates | en |
dc.subject | Cluster compounds | en |
dc.subject | N,O ligands | en |
dc.subject | Single-molecule magnets | en |
dc.title | Approaches to molecular magnetic materials from the use of cyanate groups in higher oxidation state metal cluster chemistry: Mn14 and Mn 16 | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1002/ejic.201300099 | |
dc.description.issue | 13 | |
dc.description.startingpage | 2286 | |
dc.description.endingpage | 2290 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :12</p> | en |
dc.source.abbreviation | Eur.J.Inorg.Chem. | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Alexandropoulos, Dimitris I. [0000-0002-8759-9495] | |
dc.contributor.orcid | Papatriantafyllopoulou, Constantina [0000-0002-5652-7747] | |
dc.contributor.orcid | Stamatatos, Theocharis C. [0000-0002-9798-9331] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0002-8759-9495 | |
dc.gnosis.orcid | 0000-0002-5652-7747 | |
dc.gnosis.orcid | 0000-0002-9798-9331 | |