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Synthesis and characterization of reversible and self-healable networks based on acylhydrazone groups

dc.contributor.authorApostolides, Demetris E.en
dc.contributor.authorPatrickios, Costas S.en
dc.contributor.authorLeontidis, Epameinondasen
dc.contributor.authorKushnir, M.en
dc.contributor.authorWesdemiotis, Chrystostomosen
dc.creatorApostolides, Demetris E.en
dc.creatorPatrickios, Costas S.en
dc.creatorLeontidis, Epameinondasen
dc.creatorKushnir, M.en
dc.creatorWesdemiotis, Chrystostomosen
dc.date.accessioned2019-11-21T06:16:44Z
dc.date.available2019-11-21T06:16:44Z
dc.date.issued2014
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55265
dc.description.abstractA series of seven dynamic covalent networks based on pentaerythritol tetra(benzohydrazide) and 1,10-decanediol dibenzaldehyde were prepared in N,N-dimethylformamide (DMF). The equilibrium degree of swelling in DMF and the sol fraction displayed a minimum at or near the hydrazide-benzaldehyde stoichiometric ratio. The composition of the sol fraction changed according to the feed composition, with the dibenzaldehyde-rich preparations exhibiting extractables composed of star oligomers based on tetra(benzohydrazide) cores. Finally, network reversibility and self-healing were demonstrated in the presence of acid. © 2014 Society of Chemical Industry.en
dc.sourcePolymer Internationalen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84904572310&doi=10.1002%2fpi.4724&partnerID=40&md5=e4ab4a85840a4d18e017e555722b6972
dc.subjectPolymersen
dc.subjectOrganic solventsen
dc.subjectAcylhydrazoneen
dc.subjectSynthesis and characterizationsen
dc.subjectSolsen
dc.subjectDegree of swellingen
dc.subjectDynamic polymersen
dc.subjectFeed compositionsen
dc.subjectN ,N-Dimethylformamideen
dc.subjectPolymer networksen
dc.subjectReversible bondsen
dc.subjectSelf-healingen
dc.subjectStoichiometric ratioen
dc.titleSynthesis and characterization of reversible and self-healable networks based on acylhydrazone groupsen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1002/pi.4724
dc.description.volume63
dc.description.issue9
dc.description.startingpage1558
dc.description.endingpage1565
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :10</p>en
dc.source.abbreviationPolym.Int.en
dc.contributor.orcidPatrickios, Costas S. [0000-0001-8855-0370]
dc.contributor.orcidLeontidis, Epameinondas [0000-0003-4427-0398]
dc.contributor.orcidWesdemiotis, Chrystostomos [0000-0002-7916-4782]
dc.gnosis.orcid0000-0001-8855-0370
dc.gnosis.orcid0000-0003-4427-0398
dc.gnosis.orcid0000-0002-7916-4782


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