dc.contributor.author | Archontis, Georgios Z. | en |
dc.contributor.author | Leontidis, Epameinondas | en |
dc.creator | Archontis, Georgios Z. | en |
dc.creator | Leontidis, Epameinondas | en |
dc.date.accessioned | 2019-11-21T06:16:45Z | |
dc.date.available | 2019-11-21T06:16:45Z | |
dc.date.issued | 2006 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55269 | |
dc.description.abstract | Recent experiments and simulations show that large chaotropic anions favor solvation at the water surface, mainly due to induction interactions dominated by ionic polarizabilities. We compare the solvation free-energy components of iodide at the water surface and bulk with a recent, polarizable force field. The bulk position is stabilized by the interaction between the iodide permanent charge and the solvent permanent dipole moments | en |
dc.description.abstract | the surface is favored by the iodide polarizability and the reduced cavity accommodating the solute. The ionic solvation is not described satisfactorily by linear response | en |
dc.description.abstract | the non-linearity of the iodide induced dipole moment is discussed. © 2005 Elsevier B.V. All rights reserved. | en |
dc.source | Chemical Physics Letters | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-33344469548&doi=10.1016%2fj.cplett.2005.12.051&partnerID=40&md5=c165df525b693253af37d086fb6a7bed | |
dc.subject | Polarization | en |
dc.subject | Free energy | en |
dc.subject | Organic solvents | en |
dc.subject | Method of moments | en |
dc.subject | Interfaces (materials) | en |
dc.subject | Chaotropic anions | en |
dc.subject | Dipole moments | en |
dc.subject | Iodine compounds | en |
dc.subject | Polarizable force field | en |
dc.subject | Solvent extraction | en |
dc.subject | Water surface | en |
dc.title | Dissecting the stabilization of iodide at the air-water interface into components: A free energy analysis | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/j.cplett.2005.12.051 | |
dc.description.volume | 420 | |
dc.description.issue | 1-3 | |
dc.description.startingpage | 199 | |
dc.description.endingpage | 203 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :27</p> | en |
dc.source.abbreviation | Chem.Phys.Lett. | en |
dc.contributor.orcid | Leontidis, Epameinondas [0000-0003-4427-0398] | |
dc.contributor.orcid | Archontis, Georgios Z. [0000-0002-7750-8641] | |
dc.gnosis.orcid | 0000-0003-4427-0398 | |
dc.gnosis.orcid | 0000-0002-7750-8641 | |