Spectral studies of new organic conductor (ETOEDT-PDT-TTF)2I3: Normal mode vibrations of the unsymmetrical π-electron donor
Ημερομηνία
2008Συγγραφέας
Barszcz, B.Graja, A.
Soras, Georgios
Keramidas, Anastasios D.
Tasiopoulos, Anastasios J.
Mousdis, Georgios A.
Source
Journal of Molecular StructureVolume
887Issue
1-3Pages
67-74Google Scholar check
Keyword(s):
Metadata
Εμφάνιση πλήρους εγγραφήςΕπιτομή
New donor-acceptor (ETOEDT-PDT-TTF)2I3 salt showing the layered structure was synthesized and spectrally characterized. It was shown that unsymmetrical (1,4-thioxane-2,3-diyldithio)-propylenedithiotetrathiafulvalene (ETOEDT-PDT-TTF) donor molecule with its extended shape and flexible form is a good system for salts preparation with numerous short contacts and strong intermolecular interactions. Both, Raman and infrared spectra of the donor and its iodine salt were analyzed and discussed. Important role of C{double bond, long}C vibrations was stressed. © 2008 Elsevier B.V. All rights reserved.