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Polynuclear cobalt(II/III) sulfites: Synthesis, structure, and magnetic properties of the octanuclear cluster (NH4)11(Li⊂ [Co4IICo4III(SO3) 16(NH3)8])·10H2O encapsulating a lithium cation

dc.contributor.authorChilas, G. I.en
dc.contributor.authorStylianou, Mariosen
dc.contributor.authorKubicki, Maciejen
dc.contributor.authorVaimakis, T.en
dc.contributor.authorKögerler, P.en
dc.contributor.authorKeramidas, Anastasios D.en
dc.contributor.authorKabanos, Themistoklis A.en
dc.creatorChilas, G. I.en
dc.creatorStylianou, Mariosen
dc.creatorKubicki, Maciejen
dc.creatorVaimakis, T.en
dc.creatorKögerler, P.en
dc.creatorKeramidas, Anastasios D.en
dc.creatorKabanos, Themistoklis A.en
dc.date.accessioned2019-11-21T06:17:19Z
dc.date.available2019-11-21T06:17:19Z
dc.date.issued2008
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55321
dc.description.abstractPartial oxidation of an aqueous solution of CoIICl 2·6H2O with (NH4)6[Mo 7VIO24]·4H2O in the presence of (NH4)2SO3·H2O and LiCl, at pH ≈ 5.3, leads to isolation of the octanuclear cluster (NH 4)11(Li⊂[Co4IICo 4III(SO3)16(NH3) 8]·10H2O), 1. The structure of the anion of 1 consists of a central [Co4II], almost ideal square planar unit, and a pair of symmetry-related CoIII dimers above and below the Co4II plane grafting onto the tetramer by 16 bridging sulfite groups. The [Co8(SO3)16(NH 3)8]12- cluster encapsulates a lithium cation which lies at the center of the Co4II square. © 2008 American Chemical Society.en
dc.sourceInorganic chemistryen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-46749085576&doi=10.1021%2fic8004213&partnerID=40&md5=24e7c0254a7e78e7ed050cbd0c2acc5b
dc.titlePolynuclear cobalt(II/III) sulfites: Synthesis, structure, and magnetic properties of the octanuclear cluster (NH4)11(Li⊂ [Co4IICo4III(SO3) 16(NH3)8])·10H2O encapsulating a lithium cationen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ic8004213
dc.description.volume47
dc.description.issue11
dc.description.startingpage4451
dc.description.endingpage4453
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :19</p>en
dc.source.abbreviationInorg.Chem.en
dc.contributor.orcidKeramidas, Anastasios D. [0000-0002-0446-8220]
dc.contributor.orcidKabanos, Themistoklis A. [0000-0001-6944-5153]
dc.gnosis.orcid0000-0002-0446-8220
dc.gnosis.orcid0000-0001-6944-5153


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