Introducing Dimensionality to the Archetypical Mn12 Single-Molecule Magnet: A Family of [Mn12]n Chains
Date
2016Author
Corrales, S. A.Cain, J. M.
Uhlig, K. A.
Mowson, A. M.
Papatriantafyllopoulou, Constantina
Peprah, M. K.
Ozarowski, A.
Tasiopoulos, Anastasios J.
Christou, George
Meisel, M. W.
Lampropoulos, Christos
Source
Inorganic chemistryVolume
55Issue
4Pages
1367-1369Google Scholar check
Metadata
Show full item recordAbstract
The [Mn12O12(O2CR)16(L4)] family (R = various L = terminal ligand) of clusters holds a special place in molecular magnetism they are the most well-studied single-molecule magnets (SMMs). Targeted linkage of these SMMs has now been achieved for the first time. The resulting chain structures have been confirmed crystallographically, and the magnetic properties, up to 1.14 GPa, and high-field electron paramagnetic resonance spectra have been collected and analyzed. © 2016 American Chemical Society.