dc.contributor.author | Efstathiou, Angelos M. | en |
dc.contributor.author | Bennett, C. O. | en |
dc.creator | Efstathiou, Angelos M. | en |
dc.creator | Bennett, C. O. | en |
dc.date.accessioned | 2019-11-21T06:18:50Z | |
dc.date.available | 2019-11-21T06:18:50Z | |
dc.date.issued | 1989 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55431 | |
dc.description.abstract | Various hydrogen titrations yield the surface composition of Rh Al2O3 during the CO H2 reaction at temperatures in the range 180-260 °C. There is a very small amount of active carbon Ca, 0.02-0.06 monolayer, and 0.70-0.98 monolayer of CO on the metal surface. The coverage of H is low. Also present are inactive carbon Cβ on the metal and formate species on the support. The surface coverages are consistent with the observed steady-state kinetics, which result in methane as the predominant product. Although the rate-limiting step may be the dissociation of surface CO, it is found that the reaction sequence passes through a small coverage of highly active surface carbon Cα. © 1989. | en |
dc.source | Journal of Catalysis | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0039165252&doi=10.1016%2f0021-9517%2889%2990255-8&partnerID=40&md5=020792bda740d2450a9e13e71caaa21a | |
dc.title | The CO H2 reaction on Rh Al2O3. I. Steady-state and transient kinetics | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/0021-9517(89)90255-8 | |
dc.description.volume | 120 | |
dc.description.issue | 1 | |
dc.description.startingpage | 118 | |
dc.description.endingpage | 136 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :41</p> | en |
dc.source.abbreviation | J.Catal. | en |
dc.contributor.orcid | Efstathiou, Angelos M. [0000-0001-8393-8800] | |
dc.gnosis.orcid | 0000-0001-8393-8800 | |