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dc.contributor.authorElladiou, Mariosen
dc.contributor.authorPatrickios, Costas S.en
dc.creatorElladiou, Mariosen
dc.creatorPatrickios, Costas S.en
dc.date.accessioned2019-11-21T06:18:58Z
dc.date.available2019-11-21T06:18:58Z
dc.date.issued2017
dc.identifier.issn0887-624X
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55465
dc.description.abstractA novel degradable inimer for atom transfer radical polymerization (ATRP), 2-(6-(2-((2-bromo-2-methylpropanoyl)oxy)ethyl)pyridin-2-yl)ethyl methacrylate (PyDEBrMΑ), was synthesized by the two-step esterification of 2,6-pyridinediethanol, first with α-bromoisobutyryl bromide in order to introduce the initiator moiety, and then with methacryloyl chloride in order to introduce the monomer moiety. PyDEBrMA was subsequently used to initiate the self-condensing ATRP of methyl methacrylate (MMA) to obtain a hyperbranched MMA homopolymer which could be cleaved at the PyDEBrMA residue either by treatment under mildly alkaline hydrolysis conditions (sodium deuteroxide in d6-DMSO at room temperature) or thermolysis at 150 °C. The lability of the PyDEBrMA residue arises from the presence in its structure of two 2-(pyridin-2-yl)ethyl ester moieties. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2831–2839. © 2017 Wiley Periodicals, Inc.en
dc.sourceJournal of Polymer Science, Part A: Polymer Chemistryen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85021276579&doi=10.1002%2fpola.28689&partnerID=40&md5=46f1c9580d51e512738ff0e000d0be19
dc.subjectPolymerizationen
dc.subjectEthyl methacrylatesen
dc.subjectEstersen
dc.subjectAtom transfer radical polymerizationen
dc.subjectPolymer blendsen
dc.subjectAcrylic monomersen
dc.subjectFree radical reactionsen
dc.subjectHydrolysisen
dc.subjectAtomsen
dc.subject2,6-pyridinediethanolen
dc.subjectalkaline hydrolysisen
dc.subjectatom transfer radical polymerization (ATRP)en
dc.subjectthermolysisen
dc.subject2-(6-(2-((2-bromo-2-methylpropanoyl)oxy)ethyl)pyridin-2-yl)ethyl methacrylateen
dc.subjectdegradable polymersen
dc.subjectinimeren
dc.subjectself-condensing vinyl polymerizationen
dc.titleA degradable atom transfer radical polymerization inimer: Synthesis, polymerization, and cleavage of the resulting polymer productsen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1002/pola.28689
dc.description.volume55
dc.description.issue17
dc.description.startingpage2831
dc.description.endingpage2839
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.source.abbreviationJ.Polym.Sci.Part Aen
dc.contributor.orcidPatrickios, Costas S. [0000-0001-8855-0370]


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