dc.contributor.author | Elladiou, Marios | en |
dc.contributor.author | Patrickios, Costas S. | en |
dc.creator | Elladiou, Marios | en |
dc.creator | Patrickios, Costas S. | en |
dc.date.accessioned | 2019-11-21T06:18:58Z | |
dc.date.available | 2019-11-21T06:18:58Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0887-624X | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55465 | |
dc.description.abstract | A novel degradable inimer for atom transfer radical polymerization (ATRP), 2-(6-(2-((2-bromo-2-methylpropanoyl)oxy)ethyl)pyridin-2-yl)ethyl methacrylate (PyDEBrMΑ), was synthesized by the two-step esterification of 2,6-pyridinediethanol, first with α-bromoisobutyryl bromide in order to introduce the initiator moiety, and then with methacryloyl chloride in order to introduce the monomer moiety. PyDEBrMA was subsequently used to initiate the self-condensing ATRP of methyl methacrylate (MMA) to obtain a hyperbranched MMA homopolymer which could be cleaved at the PyDEBrMA residue either by treatment under mildly alkaline hydrolysis conditions (sodium deuteroxide in d6-DMSO at room temperature) or thermolysis at 150 °C. The lability of the PyDEBrMA residue arises from the presence in its structure of two 2-(pyridin-2-yl)ethyl ester moieties. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2831–2839. © 2017 Wiley Periodicals, Inc. | en |
dc.source | Journal of Polymer Science, Part A: Polymer Chemistry | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85021276579&doi=10.1002%2fpola.28689&partnerID=40&md5=46f1c9580d51e512738ff0e000d0be19 | |
dc.subject | Polymerization | en |
dc.subject | Ethyl methacrylates | en |
dc.subject | Esters | en |
dc.subject | Atom transfer radical polymerization | en |
dc.subject | Polymer blends | en |
dc.subject | Acrylic monomers | en |
dc.subject | Free radical reactions | en |
dc.subject | Hydrolysis | en |
dc.subject | Atoms | en |
dc.subject | 2,6-pyridinediethanol | en |
dc.subject | alkaline hydrolysis | en |
dc.subject | atom transfer radical polymerization (ATRP) | en |
dc.subject | thermolysis | en |
dc.subject | 2-(6-(2-((2-bromo-2-methylpropanoyl)oxy)ethyl)pyridin-2-yl)ethyl methacrylate | en |
dc.subject | degradable polymers | en |
dc.subject | inimer | en |
dc.subject | self-condensing vinyl polymerization | en |
dc.title | A degradable atom transfer radical polymerization inimer: Synthesis, polymerization, and cleavage of the resulting polymer products | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1002/pola.28689 | |
dc.description.volume | 55 | |
dc.description.issue | 17 | |
dc.description.startingpage | 2831 | |
dc.description.endingpage | 2839 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.source.abbreviation | J.Polym.Sci.Part A | en |
dc.contributor.orcid | Patrickios, Costas S. [0000-0001-8855-0370] | |
dc.gnosis.orcid | 0000-0001-8855-0370 | |