dc.contributor.author | Ioannidou, Heraklidia A. | en |
dc.contributor.author | Kizas, Christos M. | en |
dc.contributor.author | Koutentis, Panayiotis Andreas | en |
dc.creator | Ioannidou, Heraklidia A. | en |
dc.creator | Kizas, Christos M. | en |
dc.creator | Koutentis, Panayiotis Andreas | en |
dc.date.accessioned | 2019-11-21T06:19:23Z | |
dc.date.available | 2019-11-21T06:19:23Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55555 | |
dc.description.abstract | A series of 3-chloro-5-halo(pseudohalo)-4H-1,2,6-thiadiazin-4-ones (halo/pseudohalo = Br, I, OTf) are prepared from 3,5-dichloro-4H-1,2,6- thiadiazin-4-one (3) in good yields. Of these the triflate reacts with tributyltin arenes (Stille couplings) chemoselectively to give only the 5-aryl-3-chloro-4H-1,2,6-thiadiazin-4-ones in high yields. This allowed the preparation of a series of unsymmetrical biaryl thiadiazines and ultimately a series of oligomers. Furthermore, treatment of 3-chloro-5-iodo-4H-1,2,6- thiadiazin-4-one (10) with Bu3SnH and Pd(OAc)2 gave the bithiadiazinone which can also be further arylated via the Stille reaction to give bisthien-2-yl and bis(N-methylpyrrol-2-yl) analogs. © 2011 American Chemical Society. | en |
dc.source | Organic letters | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-80055089621&doi=10.1021%2fol2025235&partnerID=40&md5=d7cc59f4ce562d55813ebc4288a41593 | |
dc.title | Selective stille coupling reactions of 3-chloro-5-halo(pseudohalo)-4 H -1,2,6-thiadiazin-4-ones | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1021/ol2025235 | |
dc.description.volume | 13 | |
dc.description.issue | 21 | |
dc.description.startingpage | 5886 | |
dc.description.endingpage | 5889 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :12</p> | en |
dc.source.abbreviation | Org.Lett. | en |
dc.contributor.orcid | Koutentis, Panayiotis Andreas [0000-0002-4652-7567] | |
dc.gnosis.orcid | 0000-0002-4652-7567 | |