| dc.contributor.author | Ioannou, P. V. | en |
| dc.contributor.author | Vachliotis, D. G. | en |
| dc.contributor.author | Nastopoulos, Vassilios | en |
| dc.contributor.author | Tasiopoulos, Anastasios J. | en |
| dc.creator | Ioannou, P. V. | en |
| dc.creator | Vachliotis, D. G. | en |
| dc.creator | Nastopoulos, Vassilios | en |
| dc.creator | Tasiopoulos, Anastasios J. | en |
| dc.date.accessioned | 2019-11-21T06:19:28Z | |
| dc.date.available | 2019-11-21T06:19:28Z | |
| dc.date.issued | 2009 | |
| dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55577 | |
| dc.description.abstract | Palladium(II) acetate in non-deaerated chloroform splits Bunsen's cacodyl disulfide, Me2As(S)-S-AsMe2, giving the complex (Me 2AsS2J2Pd, slightly soluble in chloroform, and the arsonium ion Me2As:+. However, after a few minutes the complex reacted giving Me2As(S)-O-As(S)Me2 and other, so far unidentified compounds. Therefore, the complex (Me2AsS 2J2Pd was prepared from sodium dimethyldithioarsinate dihydrate, Me2AsS2Na-2H2O, and palladium(II) acetate. (Me2AsS2)2Pd reacts with Pd 11 and Ph3P in a different way compared to other (Me 2AsS2)xM (M = heavy metal cation) and (Me 2PS2J2Pd. The reaction of equimolar quantities of Me2AsS2Na-2H2O and Ph3P under argon involved four consecutive reactions with Me2As-O-AsMe 2 and Me2AsS2Na as the final products. The salt Me2AsS2Na-2H2O has been structurally characterized: triclinic, P1, a = 6.0285(2) A, b = 6.5552(2) Å, c = 12.1480(4) Å, a = 98.282(2)°, β = 93.994(3)°, y = 115.951(3)°, V= 422.38(3) Å3, Z = 2, R1= 0.0207, wR2 = 0.0414. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. | en |
| dc.source | Zeitschrift fur Anorganische und Allgemeine Chemie | de |
| dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-70449555192&doi=10.1002%2fzaac.200900173&partnerID=40&md5=9010ceed24c688b094ce1edcfeff45ca | |
| dc.subject | Palladium | en |
| dc.subject | Arsenic | en |
| dc.subject | Dimethyldithioarsinates | en |
| dc.subject | Phosphanes | en |
| dc.subject | Structure elucidation | en |
| dc.title | Preparation and properties of sodium dimethyldithioarsinate dihydrate, Me2AsS2Na-2H2O and palladium(ii) dimethyldithioarsinate, (Me2AsS2)2Pd | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.identifier.doi | 10.1002/zaac.200900173 | |
| dc.description.volume | 635 | |
| dc.description.issue | 13-14 | |
| dc.description.startingpage | 2203 | |
| dc.description.endingpage | 2209 | |
| dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
| dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
| dc.type.uhtype | Article | en |
| dc.description.notes | <p>Cited By :8</p> | en |
| dc.source.abbreviation | Z.Anorg.Allg.Chem. | en |
| dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
| dc.contributor.orcid | Nastopoulos, Vassilios [0000-0003-4190-1342] | |
| dc.gnosis.orcid | 0000-0002-4804-3822 | |
| dc.gnosis.orcid | 0000-0003-4190-1342 | |
