dc.contributor.author | Kassi, Eleni | en |
dc.contributor.author | Patrickios, Costas S. | en |
dc.creator | Kassi, Eleni | en |
dc.creator | Patrickios, Costas S. | en |
dc.date.accessioned | 2019-11-21T06:19:50Z | |
dc.date.available | 2019-11-21T06:19:50Z | |
dc.date.issued | 2010 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55654 | |
dc.description.abstract | Tiglic acid esters are naturally derived olefins of pleasant odor but incapable of undergoing free-radical polymerization due to the steric hindrances conferred by the β-methyl group. In an effort to incorporate these green olefins in well-defined (co)polymers, we first established that methyl tiglate, the simplest tiglic acid ester, could not be polymerized using controlled polymerization techniques either, and we then introduced it in a methacrylate monomer, 2-(methacryloyloxy)ethyl tiglate (MAET), which could smoothly undergo group transfer polymerization (GTP) to yield linear polymers of narrow molecular weight distributions. Subsequently, amphiphilic and double-hydrophobic block copolymers, as well as a star polymer of MAET were obtained by its sequential GTP with 2-(dimethylamino)ethyl methacrylate, methyl methacrylate, and ethylene glycol dimethacrylate, respectively. Finally, polyMAET was selectively oxidized. © 2010 American Chemical Society. | en |
dc.source | Macromolecules | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-76149136733&doi=10.1021%2fma9023312&partnerID=40&md5=fa8b1f3f81759f4735b498ee78cc9259 | |
dc.subject | 2-(dimethylamino)ethyl methacrylate | en |
dc.subject | Controlled polymerization | en |
dc.subject | Methacrylate monomers | en |
dc.subject | Block copolymers | en |
dc.subject | Esters | en |
dc.subject | Free radical polymerization | en |
dc.subject | Acrylic monomers | en |
dc.subject | Amphiphilics | en |
dc.subject | Methyl methacrylates | en |
dc.subject | Molecular weight distribution | en |
dc.subject | Narrow molecular weight distributions | en |
dc.subject | Ethylene | en |
dc.subject | Group transfer polymerization | en |
dc.subject | Ethylene glycol | en |
dc.subject | Biodegradable polymers | en |
dc.subject | Ethylene glycol dimethacrylate | en |
dc.subject | Hydrocarbons | en |
dc.subject | Star polymers | en |
dc.subject | Acids | en |
dc.subject | Linear polymers | en |
dc.subject | Esterification | en |
dc.subject | Acid ester | en |
dc.subject | Hydrophobic blocks | en |
dc.subject | Methyl group | en |
dc.subject | Steric hindrances | en |
dc.title | Well-defined polymers from biosourced monomers: The case of 2-(methacryloyloxy)ethyl tiglate | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1021/ma9023312 | |
dc.description.volume | 43 | |
dc.description.issue | 3 | |
dc.description.startingpage | 1411 | |
dc.description.endingpage | 1415 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :10</p> | en |
dc.source.abbreviation | Macromolecules | en |
dc.contributor.orcid | Patrickios, Costas S. [0000-0001-8855-0370] | |
dc.gnosis.orcid | 0000-0001-8855-0370 | |