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dc.contributor.authorKassi, Elenien
dc.contributor.authorPatrickios, Costas S.en
dc.creatorKassi, Elenien
dc.creatorPatrickios, Costas S.en
dc.date.accessioned2019-11-21T06:19:50Z
dc.date.available2019-11-21T06:19:50Z
dc.date.issued2010
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55654
dc.description.abstractTiglic acid esters are naturally derived olefins of pleasant odor but incapable of undergoing free-radical polymerization due to the steric hindrances conferred by the β-methyl group. In an effort to incorporate these green olefins in well-defined (co)polymers, we first established that methyl tiglate, the simplest tiglic acid ester, could not be polymerized using controlled polymerization techniques either, and we then introduced it in a methacrylate monomer, 2-(methacryloyloxy)ethyl tiglate (MAET), which could smoothly undergo group transfer polymerization (GTP) to yield linear polymers of narrow molecular weight distributions. Subsequently, amphiphilic and double-hydrophobic block copolymers, as well as a star polymer of MAET were obtained by its sequential GTP with 2-(dimethylamino)ethyl methacrylate, methyl methacrylate, and ethylene glycol dimethacrylate, respectively. Finally, polyMAET was selectively oxidized. © 2010 American Chemical Society.en
dc.sourceMacromoleculesen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-76149136733&doi=10.1021%2fma9023312&partnerID=40&md5=fa8b1f3f81759f4735b498ee78cc9259
dc.subject2-(dimethylamino)ethyl methacrylateen
dc.subjectControlled polymerizationen
dc.subjectMethacrylate monomersen
dc.subjectBlock copolymersen
dc.subjectEstersen
dc.subjectFree radical polymerizationen
dc.subjectAcrylic monomersen
dc.subjectAmphiphilicsen
dc.subjectMethyl methacrylatesen
dc.subjectMolecular weight distributionen
dc.subjectNarrow molecular weight distributionsen
dc.subjectEthyleneen
dc.subjectGroup transfer polymerizationen
dc.subjectEthylene glycolen
dc.subjectBiodegradable polymersen
dc.subjectEthylene glycol dimethacrylateen
dc.subjectHydrocarbonsen
dc.subjectStar polymersen
dc.subjectAcidsen
dc.subjectLinear polymersen
dc.subjectEsterificationen
dc.subjectAcid esteren
dc.subjectHydrophobic blocksen
dc.subjectMethyl groupen
dc.subjectSteric hindrancesen
dc.titleWell-defined polymers from biosourced monomers: The case of 2-(methacryloyloxy)ethyl tiglateen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ma9023312
dc.description.volume43
dc.description.issue3
dc.description.startingpage1411
dc.description.endingpage1415
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :10</p>en
dc.source.abbreviationMacromoleculesen
dc.contributor.orcidPatrickios, Costas S. [0000-0001-8855-0370]
dc.gnosis.orcid0000-0001-8855-0370


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