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dc.contributor.authorKatsoulakou, E.en
dc.contributor.authorDermitzaki, Despinaen
dc.contributor.authorKonidaris, K. F.en
dc.contributor.authorMoushi, Eleni E.en
dc.contributor.authorRaptopoulou, Catherine P.en
dc.contributor.authorPsycharis, Vassilis P.en
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.contributor.authorBekiari, Vlasoulaen
dc.contributor.authorManessi-Zoupa, E.en
dc.contributor.authorPerlepes, Spyros P.en
dc.contributor.authorStamatatos, Theocharis C.en
dc.creatorKatsoulakou, E.en
dc.creatorDermitzaki, Despinaen
dc.creatorKonidaris, K. F.en
dc.creatorMoushi, Eleni E.en
dc.creatorRaptopoulou, Catherine P.en
dc.creatorPsycharis, Vassilis P.en
dc.creatorTasiopoulos, Anastasios J.en
dc.creatorBekiari, Vlasoulaen
dc.creatorManessi-Zoupa, E.en
dc.creatorPerlepes, Spyros P.en
dc.creatorStamatatos, Theocharis C.en
dc.description.abstractThe employment of pyridine-2,6-dimethanol (pdmH2) in zinc(II) carboxylate chemistry is reported. The syntheses, crystal structures, and spectroscopic characterization are described for the structurally similar cluster compounds [Zn6(OH)2(O2CR) 8(pdmH)2] (R = Ph (1)en
dc.description.abstractBut (2)), obtained in very good yields by the reactions between Zn(O2CR) 2·2H2O (R = Ph, But) and pdmH 2 in a 3:1 molar ratio in MeOH or MeCN solvent media, respectively. The [Zn6(μ3-OH)2(μ3-OR) 2]8+ core of both clusters can be conveniently described as four edge-sharing triangles (RO- = pdmH-). The three crystallographically unique metal ions in both 1 and 2 are found in three different coordination environments (4-, 5- and 6-coordinate), within the same molecule, a very rare case in hexanuclear Zn(II) cluster chemistry. The benzoate-analogue ZnII6 (1) displays photoluminescence with a maximum at 404 nm, upon maximum excitation at 337 nm, whereas the pivalate-analogue ZnII6 (2) shows a non-emissive characteren
dc.description.abstractthe origin of the photoluminescence is discussed.en
dc.subjectCrystal structuresen
dc.subjectIR spectroscopyen
dc.subjectMetal carboxylatesen
dc.subjectPhotoluminescent zinc(II) complexesen
dc.subjectPolynuclear zinc(II) complexesen
dc.titleHexanuclear zinc(II) carboxylate complexes from the use of pyridine-2,6-dimethanol: Synthetic, structural and photoluminescence studiesen
dc.description.endingpage475 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied SciencesΤμήμα Χημείας / Department of Chemistry
dc.description.notes<p>Cited By :8</p>en
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.contributor.orcidStamatatos, Theocharis C. [0000-0002-9798-9331]
dc.contributor.orcidRaptopoulou, Catherine P. [0000-0002-8775-5427]

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