dc.contributor.author | Katsoulakou, E. | en |
dc.contributor.author | Dermitzaki, Despina | en |
dc.contributor.author | Konidaris, K. F. | en |
dc.contributor.author | Moushi, Eleni E. | en |
dc.contributor.author | Raptopoulou, Catherine P. | en |
dc.contributor.author | Psycharis, Vassilis P. | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Bekiari, Vlasoula | en |
dc.contributor.author | Manessi-Zoupa, E. | en |
dc.contributor.author | Perlepes, Spyros P. | en |
dc.contributor.author | Stamatatos, Theocharis C. | en |
dc.creator | Katsoulakou, E. | en |
dc.creator | Dermitzaki, Despina | en |
dc.creator | Konidaris, K. F. | en |
dc.creator | Moushi, Eleni E. | en |
dc.creator | Raptopoulou, Catherine P. | en |
dc.creator | Psycharis, Vassilis P. | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Bekiari, Vlasoula | en |
dc.creator | Manessi-Zoupa, E. | en |
dc.creator | Perlepes, Spyros P. | en |
dc.creator | Stamatatos, Theocharis C. | en |
dc.date.accessioned | 2019-11-21T06:19:50Z | |
dc.date.available | 2019-11-21T06:19:50Z | |
dc.date.issued | 2013 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55656 | |
dc.description.abstract | The employment of pyridine-2,6-dimethanol (pdmH2) in zinc(II) carboxylate chemistry is reported. The syntheses, crystal structures, and spectroscopic characterization are described for the structurally similar cluster compounds [Zn6(OH)2(O2CR) 8(pdmH)2] (R = Ph (1) | en |
dc.description.abstract | But (2)), obtained in very good yields by the reactions between Zn(O2CR) 2·2H2O (R = Ph, But) and pdmH 2 in a 3:1 molar ratio in MeOH or MeCN solvent media, respectively. The [Zn6(μ3-OH)2(μ3-OR) 2]8+ core of both clusters can be conveniently described as four edge-sharing triangles (RO- = pdmH-). The three crystallographically unique metal ions in both 1 and 2 are found in three different coordination environments (4-, 5- and 6-coordinate), within the same molecule, a very rare case in hexanuclear Zn(II) cluster chemistry. The benzoate-analogue ZnII6 (1) displays photoluminescence with a maximum at 404 nm, upon maximum excitation at 337 nm, whereas the pivalate-analogue ZnII6 (2) shows a non-emissive character | en |
dc.description.abstract | the origin of the photoluminescence is discussed. | en |
dc.source | Polyhedron | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84875440991&doi=10.1016%2fj.poly.2012.08.049&partnerID=40&md5=f204771e2f9b6c087ffb3fa5f52056cd | |
dc.subject | Crystal structures | en |
dc.subject | IR spectroscopy | en |
dc.subject | Metal carboxylates | en |
dc.subject | Photoluminescent zinc(II) complexes | en |
dc.subject | Polynuclear zinc(II) complexes | en |
dc.subject | Pyridine-2,6-dimethanol | en |
dc.title | Hexanuclear zinc(II) carboxylate complexes from the use of pyridine-2,6-dimethanol: Synthetic, structural and photoluminescence studies | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/j.poly.2012.08.049 | |
dc.description.volume | 52 | |
dc.description.startingpage | 467 | |
dc.description.endingpage | 475 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :8</p> | en |
dc.source.abbreviation | Polyhedron | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Stamatatos, Theocharis C. [0000-0002-9798-9331] | |
dc.contributor.orcid | Raptopoulou, Catherine P. [0000-0002-8775-5427] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0002-9798-9331 | |
dc.gnosis.orcid | 0000-0002-8775-5427 | |