dc.contributor.author | Kourtellaris, Andreas | en |
dc.contributor.author | Moushi, Eleni E. | en |
dc.contributor.author | Spanopoulos, Ioannis | en |
dc.contributor.author | Tampaxis, Christos | en |
dc.contributor.author | Charalambopoulou, Georgia Ch | en |
dc.contributor.author | Steriotis, Theodore A. | en |
dc.contributor.author | Papaefstathìou, Giannis S. | en |
dc.contributor.author | Trikalitis, Pantelis N. | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.creator | Kourtellaris, Andreas | en |
dc.creator | Moushi, Eleni E. | en |
dc.creator | Spanopoulos, Ioannis | en |
dc.creator | Tampaxis, Christos | en |
dc.creator | Charalambopoulou, Georgia Ch | en |
dc.creator | Steriotis, Theodore A. | en |
dc.creator | Papaefstathìou, Giannis S. | en |
dc.creator | Trikalitis, Pantelis N. | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.date.accessioned | 2019-11-21T06:20:30Z | |
dc.date.available | 2019-11-21T06:20:30Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 2052-1553 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55714 | |
dc.description.abstract | A new Cu2+ complex that was isolated from the initial use of 5-((pyridin-4-ylmethylene)amino)isophthalic acid (PEIPH2) in 3d metal-organic framework (MOF) chemistry is reported. Complex {[Cu3(PEIP)2(5-NH2-mBDC)(DMF)]·7DMF}∞ denoted as Cu-PEIP·7DMF was isolated from the reaction of Cu(NO3)2·2.5H2O with PEIPH2 in N,N-dimethylformamide (DMF) at 100 °C and contains both the PEIP2- ligand and its 5-NH2-mBDC2- fragment. After the structure and properties of Cu-PEIP were known an analogous complex was prepared by a rational synthetic method that involved the reaction of Cu(NO3)2·2.5H2O, 5-((pyridin-4-ylmethyl)amino)isophthalic acid (PIPH2-the reduced analogue of PEIPH2) and 5-NH2-mBDCH2 in DMF at 100 °C. Cu-PEIP comprises two paddle-wheel [Cu2(COO)4] units and exhibits a 3D-framework with a unique trinodal underlying network and point symbol (4.52)4(42·54·64·83·92)2(52·84). This network consists of pillared kgm-a layers containing a hexagonal shaped cavity with a relatively large diameter of ∼8-9 Å surrounded by six trigonal shaped ones with a smaller diameter of ∼4-5 Å and thus resembles the structure of HKUST-1. Gas sorption studies revealed that Cu-PEIP exhibits a 1785 m2 g-1 BET area as well as high CO2 sorption capacity (4.75 mmol g-1 at 273 K) and CO2/CH4 selectivity (8.5 at zero coverage and 273 K). © 2016 This journal is the Partner Organisations. | en |
dc.source | Inorganic Chemistry Frontiers | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85000347745&doi=10.1039%2fc6qi00273k&partnerID=40&md5=805d86aeac3792c705d3ddf559a2a14d | |
dc.title | A microporous Cu2+ MOF based on a pyridyl isophthalic acid Schiff base ligand with high CO2 uptake | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/c6qi00273k | |
dc.description.volume | 3 | |
dc.description.issue | 12 | |
dc.description.startingpage | 1527 | |
dc.description.endingpage | 1535 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :2</p> | en |
dc.source.abbreviation | Inorg.Chem.Front. | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Papaefstathìou, Giannis S. [0000-0001-5514-6371] | |
dc.contributor.orcid | Trikalitis, Pantelis N. [0000-0002-6286-2955] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0001-5514-6371 | |
dc.gnosis.orcid | 0000-0002-6286-2955 | |