dc.contributor.author | Koutentis, Panayiotis Andreas | en |
dc.contributor.author | Koyioni, Maria G. | en |
dc.contributor.author | Michaelidou, Sophia S. | en |
dc.creator | Koutentis, Panayiotis Andreas | en |
dc.creator | Koyioni, Maria G. | en |
dc.creator | Michaelidou, Sophia S. | en |
dc.date.accessioned | 2019-11-21T06:20:32Z | |
dc.date.available | 2019-11-21T06:20:32Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1477-0520 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55723 | |
dc.description.abstract | The thermolysis of several N-(4-chloro-5H-1,2,3-dithiazol-5-ylidene) pyridin-n-amines (where n = 2, 3 and 4) gives a mixture of thiazolopyridine-2- carbonitriles in low to moderate yields. Introduction, by design, of a chlorine substituent at the C2 or C4 position of N-(4-chloro-5H-1,2,3-dithiazol-5- ylidene)pyridin-3-amine and other selected azines enables a BnEt3NI mediated ANRORC style ring transformation that provides fourteen heteroazine fused thiazole-2-carbonitriles in moderate to near quantitative yields. The synthesis described herein therefore provides a facile high yielding two-step route to heteroazine fused thiazole-2-carbonitriles starting from 4,5-dichloro-1,2,3-dithiazolium chloride (Appel salt) and ortho- or para-chloro substituted meta-aminoazines. © 2013 The Royal Society of Chemistry. | en |
dc.source | Organic and Biomolecular Chemistry | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84871761333&doi=10.1039%2fc2ob26993g&partnerID=40&md5=5eabbbc25ce255d0660929cf3c26b650 | |
dc.subject | Chlorine compounds | en |
dc.subject | Chlorine | en |
dc.subject | Organic compounds | en |
dc.subject | Nitrogen compounds | en |
dc.subject | Ring transformation | en |
dc.subject | Carbonitriles | en |
dc.subject | Quantitative yields | en |
dc.title | The conversion of [(4-chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines into azine fused thiazole-2-carbonitriles | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/c2ob26993g | |
dc.description.volume | 11 | |
dc.description.issue | 4 | |
dc.description.startingpage | 621 | |
dc.description.endingpage | 629 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :13</p> | en |
dc.source.abbreviation | Org.Biomol.Chem. | en |
dc.contributor.orcid | Koutentis, Panayiotis Andreas [0000-0002-4652-7567] | |
dc.contributor.orcid | Koyioni, Maria [0000-0002-2786-7523] | |
dc.gnosis.orcid | 0000-0002-4652-7567 | |
dc.gnosis.orcid | 0000-0002-2786-7523 | |