dc.contributor.author | Kyprianidou, Eleni J. | en |
dc.contributor.author | Papaefstathìou, Giannis S. | en |
dc.contributor.author | Manos, Manolis J. | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.creator | Kyprianidou, Eleni J. | en |
dc.creator | Papaefstathìou, Giannis S. | en |
dc.creator | Manos, Manolis J. | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.date.accessioned | 2019-11-21T06:21:00Z | |
dc.date.available | 2019-11-21T06:21:00Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1466-8033 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55752 | |
dc.description.abstract | A new flexible Cd2+ metal organic framework (MOF), denoted as UCY-3, which is the second example of a MOF with the ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], is reported. It shows a unique (3,3,6)-connected topology and is based on a neutral non-oxo triangular [Cd3(COO)6] secondary building unit that appears for the first time in MOFs chemistry. UCY-3 displays significant structural flexibility, capability for exchange of the guest solvents by various organic molecules in a single-crystal-to-single-crystal fashion as well as breathing capacity allowing the incorporation of relatively large amount of benzene into its pores. Overall this work indicates that MOFs based on semi-rigid polytopic ligands may adopt unprecedented structural types and exhibit unexpectedly high absorption capacities for relatively bulky organic molecules, as a result of their flexibility and breathing capability. © The Royal Society of Chemistry. | en |
dc.source | CrystEngComm | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84870535772&doi=10.1039%2fc2ce25913c&partnerID=40&md5=0ee7b8ff45f9488bbf56cc549006bce1 | |
dc.title | A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected topology, unprecedented secondary building units and single crystal to single crystal solvent exchange properties | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/c2ce25913c | |
dc.description.volume | 14 | |
dc.description.issue | 24 | |
dc.description.startingpage | 8368 | |
dc.description.endingpage | 8373 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :20</p> | en |
dc.source.abbreviation | Crystengcomm | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Papaefstathìou, Giannis S. [0000-0001-5514-6371] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0001-5514-6371 | |