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Magnetic “Molecular Oligomers” Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragment

dc.contributor.authorManoli, Mariaen
dc.contributor.authorAlexandrou, Sofiaen
dc.contributor.authorPham, Linhen
dc.contributor.authorLorusso, Giuliaen
dc.contributor.authorWernsdorfer, Wolfgangen
dc.contributor.authorEvangelisti, Marcoen
dc.contributor.authorChristou, Georgeen
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.creatorManoli, Mariaen
dc.creatorAlexandrou, Sofiaen
dc.creatorPham, Linhen
dc.creatorLorusso, Giuliaen
dc.creatorWernsdorfer, Wolfgangen
dc.creatorEvangelisti, Marcoen
dc.creatorChristou, Georgeen
dc.creatorTasiopoulos, Anastasios J.en
dc.date.accessioned2019-11-21T06:21:20Z
dc.date.available2019-11-21T06:21:20Z
dc.date.issued2015
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55823
dc.source.urihttps://nls.ldls.org.uk/welcome.html?ark:/81055/vdc_100028319888.0x00004e
dc.source.urihttps://nls.ldls.org.uk/welcome.html?ark:/81055/vdc_100028319993.0x000025
dc.subjectChemistryen
dc.titleMagnetic “Molecular Oligomers” Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragmenten
dc.typeinfo:eu-repo/semantics/article
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>ID: 1129en
dc.description.notesIn: Angewandte Chemie international edition, Vol. 55, no. 2 ( 2016), p.679-684.en
dc.description.notesSummary: AbstractTwo nanosized Mn49and Mn25Na4clusters based on analogues of the high‐spin (S=22) [MnIII6MnII4(μ4‐O)4]18+supertetrahedral core are reported. Mn49and Mn25Na4complexes consist of eight and four decametallic supertetrahedral subunits, respectively, display high virtual symmetry (Oh), and are unique examples of clusters based on a large number of tightly linked high nuclearity magnetic units. The complexes also have large spin ground‐state values (Mn49:S=61/2en
dc.description.notesMn25Na4: S=51/2) with the Mn49 cluster displaying single‐molecule magnet (SMM) behavior and being the second largest reported homometallic SMM.AbstractStacking blocks: Two nanosized Mn25Na4and Mn49clusters consisting of four and eight decametallic supertetrahedral subunits, respectively, are reported. These clusters are unique examples of oligomeric species based on magnetic subunits and have large spin ground‐state valuesS=51/2 (Mn25Na4) and 61/2 (Mn49). The Mn49cluster displays single‐molecule magnet (SMM) behavior and is the second largest reported homometallic SMM.</p>en
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.gnosis.orcid0000-0002-4804-3822


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