| dc.contributor.author | Manos, Manolis J. | en |
| dc.contributor.author | Moushi, Eleni E. | en |
| dc.contributor.author | Tasiopoulos, Anastasios J. | en |
| dc.creator | Manos, Manolis J. | en |
| dc.creator | Moushi, Eleni E. | en |
| dc.creator | Tasiopoulos, Anastasios J. | en |
| dc.date.accessioned | 2019-11-21T06:21:22Z | |
| dc.date.available | 2019-11-21T06:21:22Z | |
| dc.date.issued | 2010 | |
| dc.identifier.issn | 1565-3633 | |
| dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55831 | |
| dc.description.abstract | A new 1-D coordination polymer { [Mn6O2(O 2CMe)10 (H2O)4] 2.5 H 2O}λ (1 2.5 H2O) and the cluster [Mn 6O2(O2(O2CPh) 10(py) 2(MeCN)(H2O)] 2MeCN (2 2MeCN) are reported. Both compounds were synthesized by room temperature reactions of [Mn3(μ 3-O)(O2CR)6(L) 2 (L )] (R=Me, L= L′ =py, (1 2.5 H2O)λ | en |
| dc.description.abstract | R=Ph, L=py, L = H2O, 2 2MeCN) in the presence of 3-hydroxymethylpyridine (3hmpH) in acetonitrile. The structures of these complexes are based on hexanuclear mixed-valent manganese carboxylate clusters containing the [Mn4II Mn2 III(μ4-O)2]10+ structural core. (1 2.5 H2O) consists of zigzag chain polymers constructed from [Mn6O2(O2CMe)10(H2O) 4] repeating units linked through acetate ligands, whereas 2 2MeCN comprises a discrete Mn6-benzoate cluster. Copyright © 2010 Eleni E. Moushi et al. | en |
| dc.source | Bioinorganic Chemistry and Applications | en |
| dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-77954608002&doi=10.1155%2f2010%2f367128&partnerID=40&md5=13537eb0d05a7f3ac53ebf170f7861dc | |
| dc.title | Synthesis and structural characterization of a metal cluster and a coordination polymer based on the [Mn6(μ4-O) 2]10+ Unit | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.identifier.doi | 10.1155/2010/367128 | |
| dc.description.volume | 2010 | |
| dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
| dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
| dc.type.uhtype | Article | en |
| dc.source.abbreviation | Bioinorg.Chem.Appl. | en |
| dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
| dc.gnosis.orcid | 0000-0002-4804-3822 | |
