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A new family of octanuclear Mn complexes with a rod-like topology

dc.contributor.authorMoushi, Eleni E.en
dc.contributor.authorStamatatos, Theocharis C.en
dc.contributor.authorNastopoulos, Vassiliosen
dc.contributor.authorChristou, Georgeen
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.creatorMoushi, Eleni E.en
dc.creatorStamatatos, Theocharis C.en
dc.creatorNastopoulos, Vassiliosen
dc.creatorChristou, Georgeen
dc.creatorTasiopoulos, Anastasios J.en
dc.date.accessioned2019-11-21T06:21:38Z
dc.date.available2019-11-21T06:21:38Z
dc.date.issued2009
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55881
dc.description.abstractThree new octanuclear compounds were prepared from reactions of [Mn(O2CR)2]·2H2O (R = Et or Ph) with the diols 1,3-propanediol (pdH2) or 2-methyl-1,3-propanediol (mpdH2) in the presence of NaN3. All three compounds [Mn8(N3)4(O2CR)6(L)4(py)6] (L = pd2-, R = Et 1en
dc.description.abstractL = mpd2-, R = Et 2en
dc.description.abstractL = pd2-, R = Ph 3) (py = pyridine) possess a novel near-planar, rod-like topology. Dc and ac magnetic susceptibility studies in the 2-300 K range for complexes 1 and 2 revealed the presence of dominant antiferromagnetic exchange interactions, leading to diamagnetic ground spin states. © 2009 Elsevier Ltd. All rights reserved.en
dc.sourcePolyhedronen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-70349454062&doi=10.1016%2fj.poly.2009.05.011&partnerID=40&md5=77a96f467cb24da5ca9f4dff1e223c91
dc.subjectMagnetic propertiesen
dc.subjectCrystal structuresen
dc.subjectMn clustersen
dc.subject1,3-Propanediolen
dc.titleA new family of octanuclear Mn complexes with a rod-like topologyen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1016/j.poly.2009.05.011
dc.description.volume28
dc.description.issue15
dc.description.startingpage3203
dc.description.endingpage3208
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.source.abbreviationPolyhedronen
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.contributor.orcidStamatatos, Theocharis C. [0000-0002-9798-9331]
dc.contributor.orcidNastopoulos, Vassilios [0000-0003-4190-1342]
dc.gnosis.orcid0000-0002-4804-3822
dc.gnosis.orcid0000-0002-9798-9331
dc.gnosis.orcid0000-0003-4190-1342


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